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Title:
PLANT BASED VEGAN LEATHER MADE FROM BANANA CROP-WASTE
Document Type and Number:
WIPO Patent Application WO/2024/042538
Kind Code:
A1
Abstract:
The present invention relates to compositions for preparing Vegan Leather and Vegan Leather prepared from such compositions wherein such compositions comprise of Banana pulp and at least one adhesive or binder. Further, the invention also relates to processes for preparing compositions and Vegan Leather from compositions containing Banana Pulp. This Vegan leather is a leather like material completely free of any animal product.

Inventors:
MODY JINALI (IN)
SHRIVASTAVA SHSHANK (IN)
PAUL SULATA (IN)
Application Number:
PCT/IN2023/050788
Publication Date:
February 29, 2024
Filing Date:
August 21, 2023
Export Citation:
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Assignee:
MODY JINALI (IN)
International Classes:
B32B23/00; B32B7/12; B32B23/02; B32B23/04; B32B23/10; D06N3/02
Domestic Patent References:
WO2021121509A22021-06-24
Foreign References:
CN104164800A2014-11-26
CN107141603A2017-09-08
IN202221054824A2022-10-07
Other References:
HENDRIKSZ VIVIAN: "Sustainable Textile Innovations: Banana Fibres", FASHIONUNITED, 28 August 2017 (2017-08-28), XP093144746, Retrieved from the Internet [retrieved on 20240322]
NGUYEN TUAN ANH, NGUYEN THI HUONG: "Study on Mechanical Properties of Banana Fiber-Reinforced Materials Poly (Lactic Acid) Composites", INTERNATIONAL JOURNAL OF CHEMICAL ENGINEERING, HINDAWI PUBLISHING CORPORATION, US, vol. 2022, 29 June 2022 (2022-06-29), US , pages 1 - 7, XP093144747, ISSN: 1687-806X, DOI: 10.1155/2022/8485038
KARIMAH AZIZATUL, RIDHO MUHAMMAD RASYIDUR, MUNAWAR SASA SOFYAN, ISMADI, AMIN YUSUP, DAMAYANTI RATIH, LUBIS MUHAMMAD ADLY RAHANDI, : "A Comprehensive Review on Natural Fibers: Technological and Socio-Economical Aspects", POLYMERS, MOLECULAR DIVERSITY PRESERVATION INTERNATIONAL (M DP I) AG., CH, vol. 13, no. 24, CH , pages 4280, XP093144748, ISSN: 2073-4360, DOI: 10.3390/polym13244280
Attorney, Agent or Firm:
KHARKAR, Pallavi et al. (IN)
Download PDF:
Claims:
Claims

We claim

1. A composition for preparing a Vegan Leather comprising banana pulp made from banana pseudostems and at least one adhesive or binder.

2. The composition as claimed in claim 1 for spraying, coating, or applying on a backing material to produce Vegan Leather.

3. The composition as claimed in claim 1 comprising two or more adhesives, two or more binders or at least one adhesive and one binder.

4. The composition as claimed in claim 1 further comprising other additives selected from the group comprising filler, softener / plasticizer, preservative.

5. The composition of claim 1 wherein banana pulp is produced by processing banana crop waste containing banana pseudostems and banana pseudostem fibres.

6. The composition as claimed in claim 1 wherein Banana pulp is from 40 - 70 % w/w.

7. The composition as claimed in claim 1 wherein at least one adhesive and / or binder from 5 - 50 % w/w.

8. The composition as claimed in claim 4 wherein filler is from 5 - 35 % w/w.

9. The composition as claimed in claim 4 wherein softener is from 1 - 15 % w/w.

10. The composition as claimed in claim 4 wherein preservative is from 0.01 - 0.1 % w/w.

11. The composition as claimed in claim 1 wherein adhesive is selected from neoprene, natural rubber, ethylene vinyl acetate, polyvinyl acetate, gum arabic solution, gum rosin solution, guar gum, jackfruit glue, agar agar solution, banyan sap, arrowroot flour or glue, corn-starch adhesive or a combination of adhesives.

12. The composition of claim 1 wherein binder is selected from poly lactic acid, maleic anhydride, polyvinyl chloride, polyurethane, bio polyurethane, acrylic binder, resin binder and starch.

13. The composition as claimed in claim 1 wherein softener / plasticizer is selected from polyethylene glycol, polypropylene glycol, glycerol, isopropyl alcohol, citric acid, fruit waxes, paraffin waxes, vegetable or fruit oils comprising Com oil, Sunflower oil, palm oil and epoxidized vegetable oils.

14. The composition as claimed in claim 4 wherein filler is selected from i) Starch from tapioca, rice, com, potato, ii) rice husk, iii) cork filler, iv) polymer filler comprising one or more of Magnopal IPF, Magnopal BP, Magnopal Pure-A, v) one or more waxes, vi) one or more agri-waste filler, vii) wheat straw, viii) vegetable oil; ix) talcum powder.

15. Vegan Leather comprising backing material coated with composition comprising banana pulp and at least one adhesive or binder.

16. The Vegan Leather as claimed in claim 15 further comprising one or more of filler, softener / plasticizer, preservative in the composition coated on the backing material.

17. The Vegan Leather as claimed in claim 15 wherein composition comprising banana pulp and at least one adhesive or binder is sprayed, coated, or applied on the backing material as one or two or multiple coatings.

18. The Vegan Leather as claimed in claim 15 further comprising one or more of dyes, pigments, binders, lacquers, preservatives, and water resistant / water repellent coatings.

19. The Vegan Leather as claimed in claim 15 wherein backing material is selected from recycled plastic bottles fabric, polyester, nylon, velvet, cotton fabric, and natural fabrics made from organic cotton, banana fibre, bamboo, jute, linen, rayon.

20. The Vegan Leather as claimed in claim 15 comprising from 40 - 70 % banana fibres / banana pulp.

21. The Vegan Leather as claimed in claim 15 comprising from 50 - 65 % banana fibres / banana pulp.

22. The Vegan Leather as claimed in claim 18 wherein lacquer is selected from nitrocellulose lacquer, polyurethane lacquer, acrylic lacquer, and water-based silicone emulsion.

23. The Vegan Leather as claimed in claim 15 wherein backing material comprises up to 20 %, preferably up to 10 % and more preferably up to 5 %.

24. The Vegan Leather as claimed in claim 18 comprising from 1 - 15 % of backing material, colours / pigments, binders, lacquers, chemicals to prevent colour leakage and water repellents and 85 - 99 % of coating composition containing Banana pulp and at least one adhesive / binder and optionally one or more of other additives such as fillers and softeners / plasticizers and from 0.001 to 0.1 % w/w of preservatives.

25. Vegan Leather as claimed in claim 15 having three or more; preferably four or more, more preferably five or more, and most preferably seven or more of the following properties / characteristics i) banana pulp content from 50 - 65 % w/w; ii) thickness from 0.7mm to 1.4mm. iii) tensile strength from 10 - 20 N/ mm2.; iv) flexing and elongation 25 - 35% v) tearing strength from 30 - 80 N/mm; vi) no abrasion or coating removal in dry condition up to 500 revolution; vii) moisture content not more than 3 %; viii) water vapour permeability up to 0.5 mg/cm2/h; ix) water vapour absorption up to up to 2 mg/cm2 x) phthalate free, lead free, chrome free, cadmium free, zinc free Vegan Leather.

26. A process of preparing compositions which are coated / sprayed on backing material to produce Vegan Leather wherein the process comprises v) Preparing banana pulp from banana pseudostems; vi) Mixing banana pulp and adhesive / binder in a blender; vii) Optionally adding any additional adhesive and / or binder; or adding filler and / or softener and blending further; viii) Mixing dyes / pigments / synthetic colour with a binder and adding the mixture to above blend while mixing. ix) Coating, spraying, applying the above mixture to a backing material x) Mechanized treatment of top layer with pressure and heat in the form of embossing, plating to form leather patterns xi) Applying one or more final layers of coating with preservatives, water resistant chemicals, dyes, binders, and lacquers.

27. The process of preparing compositions as claimed in claim 26 wherein banana pulp is prepared by comprising vii) Preparing or obtaining banana psuedostems in the form of stem cuttings and stem fibre after fruit has been harvested; viii) Subjecting banana fibre and stem cuttings to alkali treatment; ix) Boiling banana fibre and stem cuttings in a suitable equipment or digester causing them to form banana pulp; x) Washing and straining pulp to wash out left over alkali; xi) Grinding pulp and washing ground pulp; xii) Optionally bleaching the pulp and washing pulp to wash out bleaching agent.

28. The process of preparing compositions as claimed in claim 27 wherein banana pulp is subjected to bleaching using water and one or more of bleaching agents selected from calcium hypochlorite, sodium hypochlorite, liquid bleach, hydrogen peroxide, sodium percarbonate, sodium perborate and washing the pulp after bleaching.

29. A process of preparing Vegan Leather comprising viii) Selecting and cutting backing material in suitable dimensions; ix) Preparing pulp from banana pseudo-stem or pseudo-fibre. x) Preparing coating compositions; xi) Applying or spraying coating compositions on the backing material of suitable sizes to obtain panels; xii) Trowelling panels or spreading even the coated composition on panels; xiii) Drying panels under controlled temperature; xiv) Plating dried panels; xv) Subjecting plated panels to colour spraying, drying and surface treatments comprising one or more of, milling, embossing, and lacquering.

Or xiii) Providing mechanized treatment of top layer with pressure and heat in the form of embossing, plating to form leather patterns xiv) Applying one or more final layers of coating with preservatives, water resistant chemicals, dyes, binders, and lacquers.

30. The process of preparing Vegan Leather as claimed in claim 29 comprising adding i) chemicals to prevent colour leakage and / or ii) water repellents during surface treatment.

Description:
Plant based Vegan Leather made from banana crop -waste

Field of the invention

The present invention relates to compositions for preparing Vegan Leather and Vegan Leather prepared from such compositions. This Vegan leather is a leather like material completely free of any animal product. Particularly, the invention relates to compositions for preparing Vegan Leather wherein such compositions and Vegan Leather are prepared from Banana crop waste including banana pseudostems. More particularly, compositions and Vegan Leather are prepared from processed Banana crop waste such as Banana pulp. Compositions for preparing Vegan Leather comprise of Banana pulp and at least one adhesive or binder. Further, the invention also relates to processes for preparing compositions and Vegan Leather from compositions containing Banana Pulp.

Objects of the invention

First object of the invention is to provide compositions to prepare Plant based Vegan Leather wherein the compositions are completely free of animal product and thus avoids animal cruelty of the leather industry.

Second object of the invention is to provide compositions to prepare Plant based Vegan Leather wherein the compositions are employed in manufacturing Vegan Leather by a tanning free process.

Third object of the present invention to provide a solution for leather manufacturing that causes minimal or zero pollution and majority of the material (>50%) is natural.

Fourth object of the present invention is to provide a solution for leather manufacturing that addresses the growing crop waste problem.

Fifth object of the invention is to use waste from the Banana crop after Harvest to prepare compositions which can be further employed in Vegan Leather manufacturing. Therefore, the Vegan Leather is prepared from compositions which employ easily and abundantly available raw materials. Sixth object of the invention is to provide a simple, economical and environment friendly process to prepare Plant based Vegan Leather from compositions of the present invention containing processed waste from Banana crop.

Seventh object of the present invention is to provide a vegan leather material which looks, feels, and performs like leather.

Eighth object of the present invention is to develop sustainable and environmentally friendly alternatives which are significantly lower water intensive in comparison to animal leather manufacturing and lower carbon emissions

Ninth object of the present invention is to develop plant leather alternative with over 50% banana crop waste.

Summary of the invention

It is reported that leather is a by-product of animal slaughter for meat, however, in reality, leather is a valuable co-product, and over one billion animals are slaughtered for their skin worldwide every year.

Present invention provides Plant based Vegan Leather completely free of any animal product.

Under the first aspect, the invention provides compositions to prepare Plant based Vegan Leather wherein the compositions are completely free of animal product. The said compositions incorporate plant based materials, particularly, plant based waste material which is otherwise discarded. Using plant based materials for manufacturing compositions of the present invention completely eliminates use of animal skins or animal products in manufacturing of leather.

Tanning process used typically in manufacturing of leather employs harsh and toxic chemicals that are largely deposited untreated into wastewater responsible for polluting many water bodies. Various types of Tanning processes typically involve use of basic chromium sulfate (BCS) and other toxic metals. Such use enhances Carcinogenic compounds in the wastewater like Cr(VI), Cadmium, Arsenic etc. which are known carcinogens. Additionally, chemicals like formaldehyde, lead, zinc, silicon are traced which are also hazardous. Therefore, stringent norms are applicable for estimating presence or formation of Cr (VI) in the final leather.

Manufacturing leather without requiring tanning step offers several ecological and environmental benefits such as reduction in water used, generation of toxic waste and significant reduction in carbon emissions.

Under the second aspect, the invention provides compositions to prepare Plant based Vegan Leather wherein the compositions are employed in manufacturing Vegan Leather by a tanning free process.

Under the third aspect, the present invention uses easily and abundantly available raw material to manufacture compositions which are further used to prepare Plant based Vegan Leather.

Under this aspect, invention uses waste from the Banana crop after Harvest to prepare compositions which can be further employed in Vegan Leather manufacturing. Therefore, the Vegan Leather is prepared from compositions which employ easily and abundantly available raw material such as Banana crop waste.

Leather manufacturing is a complex process. It involves a series of processes to arrive at a leather having desirable characteristics. The processes involved are soaking, liming, deliming, bating, pickling, tanning, dyeing, and finishing, and the other machinery steps like splitting, sammying, staking, drumming etc. Each one of these processes is complicated and requires multiple steps with immense water and energy used.

Fourth object of the invention is to provide a simple, economical and environment friendly process to prepare i) Compositions of the present invention containing Banana pulp which is obtained by processed waste from Banana crop and ii) Plant based Vegan Leather from compositions of the present invention. The process does not involve use of any toxic or hazardous chemical and the product produced is free of any such chemicals. Background of the Invention

The leather industry is responsible for significant environmental damage and puts immense pressure on land, food, water resources and animal livestock too. A typical cow leather bag requires 18,000 liters of water which is 25 years of drinking water for a single person and the carbon equivalent of charging 12,000 smartphones. This can also be looked at as the emissions from the manufacturing of 100K straws.

14% w/w of all emissions globally are attributed to livestock rearing an industry that leather depends on. Additionally, 1 ton of raw material generates 20% w/w of finished leather and 60-80% w/w of solid and liquid waste that includes carcinogenic heavy metals, a by-product of the tanning processes. 90% w/w of leather processed is tanned using chromium and other toxic chemicals that are largely deposited untreated into wastewater responsible for polluting many water bodies.

Countries like India are responsible for the most crop residue burning from any other country, which is 18 Mn tons a year leading to some of the most polluted cities in the world.

Specifically, the banana crop has more waste than most other crops as the plant only bears fruit once, after which the stem becomes redundant. 80% w/w of the plant by weight is wasted every harvest which amounts to about 120< tones generated annually. And < 10% w/w of this cellulose and fibre rich waste is utilized despite its high value.

Indian Patent Application No. 202221054824 A provides a non-woven banana plant leather made of banana fiber, which is extracted from banana stem. The extracted banana fibers are opened, carded, cross-lapped and needle punched to obtain banana fiber substrate which is a single layer non-woven substrate having density ranging from 1.5 to 2 g/mm3. The banana fiber substrate is coated with adhesive coat to form composite with bio polyurethane in ratio of range of 3:0.1:1 to 5:0.1: 1 to give desired leather finish to the banana fiber substrate. This prior art utilizes banana for preparing backing material wherein strength of Banana stem is not fully utilized. There is a need for vegan leather in the market today, however, due to the vastly different supply chains and production processes, it is not possible for traditional manufacturers of animal leather to convert or switch to plant leather production. Additionally, the majority of vegan leather alternatives are polyurethane, and PVC based, both from petrochemical sources, which is not sustainable and environmentally friendly. There are some new plant-based alternatives in the market from cactus, mycelium, yeast and other raw materials, however such plantbased alternatives are also scarcely applicable.

Brief Description of figures

For a better understanding of the embodiments of the machine and methods described herein, and to show more clearly how they may be carried into effect, references will now be made, by way of example, to the accompanying drawings, wherein like reference numerals represent like elements/components throughout and wherein:

Fig.l illustrates an exemplary flowchart that shows a plant-based method for manufacturing plant based vegan leather material, in accordance with an embodiment of the present invention.

Fig. 2 illustrates an exemplary view showing the plant-based panels of banana stem leather, in accordance of the present invention.

Fig.3 provides a process diagram depicting all steps in preparing plant based vegan leather of the present invention.

Fig. 4 provides different steps involved in the preparation for the plant based vegan leather starting from harvesting banana tree to finished product.

Fig. 5 and Fig.6 provides plant based vegan leather prepared as per the present invention.

Fig. 7A provides the composition containing banana pulp produced by processing banana crop waste and other additives which is used for preparing plant based vegan leather. Fig. 7B provides the coating of composition of Fig. 7A by way of spraying, on the backing material to produce leather.

Fig. 7C provides the plant based vegan leather produced after coating of composition containing banana pulp produced by processing banana crop waste and other additives.

Fig. 8 provides the plant based vegan leather prepared as per the present invention.

Fig. 9 provides spraying of lacquering suspension.

Fig. 10 provides a wallet prepared as per the present invention.

Fig. 11A and Fig. 1 IB provides picture of bags prepared by using plant-based vegan leather prepared as per the present invention.

Fig. 12A and Fig. 12B provides a test reports of banana content (%) and other content (%) of the plant-based vegan leather prepared as per the present invention. Fig. 13 A provides image of Vegan Leather wherein of composition o having 60% Banana pulp + 30 % natural rubber + 10 % natural adhesive

Fig. 13 B provides image of Vegan Leather wherein of composition q having 60% Banana pulp + 30 % natural rubber + 10 % Arrowroot Glue

Fig. 14 A provides image of Vegan Leather wherein of composition U having 55% Banana pulp + 26 % polyvinyl acetate + 14 % acrylic +5 % starch as filler.

Fig. 14 B provides image of Vegan Leather wherein of composition q having 60% Banana pulp + 30 % natural rubber + 10 % Arrowroot Glue.

Fig. 15A provides image of Vegan Leather wherein of composition R having 55% Banana pulp + 25 % polyvinyl acetate + 20 % Magnopal IPF

Fig. 15B provides image of Vegan Leather wherein of composition V having 60% Banana pulp + 30 % polyvinyl acetate + 10 % PEG.

Detailed description of the invention

The invention provides compositions to produce plant based vegan leather and Vegan leather produced from such compositions. Mainly, the invention provides compositions containing processed banana crop waste which are further used to produce vegan leather. Particularly, the invention covers compositions containing i) Banana pulp produced by processing banana crop waste and ii) other additives. More particularly, the invention covers compositions containing i) Banana pulp and ii) at least one adhesive / binder and optionally other additives selected from fillers, softeners / plasticizers, preservatives etc. . .

These compositions are coated on the backing material to produce leather. Hence the compositions of the present invention are also referred as “coating compositions”. These compositions are also referred as leather mixtures.

The invention further provides leather produced by depositing / spraying / applying coating compositions / leather mixtures of the present invention on backing material. The leather produced is further subjected through various processes to enhance adhesion between backing material and coated composition and to enhance look of a leather. These processes include plating, colour spraying, embossing and lacquering and drying in between these steps whenever required.

The plant-based vegan leather material looks, feels and performs like leather.

The vegan leather and compositions from which it is prepared do not contain any animal product. The processes to prepare compositions and Vegan Leather are tanning free processes. The compositions and Vegan Leather are prepared from raw materials which are easily and abundantly available and processes are simple, economical and environment friendly.

Central to this innovations are the compositions that meld around 40 - 70 % w/w of banana pulp, from 5 - 50 % w/w of adhesive and / or binder and optionally other additives into a cohesive and versatile mixture. The amalgamation of these components is a strategic endeavour aimed at crafting compositions with distinctive properties. The abundant presence of banana pulp, constituting almost half of the mixture serves as a foundational element. Its natural binding attributes, coupled with inherent biodegradability, offer a sustainable adhesive quality.

More particularly, compositions to produce Vegan Leather are made from processed Banana crop waste. Banana crop generates significant waste than most other crops as the plant only bears fruit once, post which the stem becomes redundant and needs to be cut and discarded. Banana crop generates significant waste than most other crops as the plant only bears fruit once, post which the stem becomes redundant and needs to be cut and discarded. Thus 80% w/w of the plant by weight is wasted every harvest which amounts to about over 120 million metric < tones are generated annually globally. For India, which produces 25% w/w of the world's bananas, the waste generated is 30 million metric tons. And <10% w/w of this cellulose and fibre rich waste is utilized despite its high value. Thus, the present invention utilizes abundantly and easily available raw materials which are usually discarded as waste.

The present plant-based vegan leather is prepared from banana crop waste and thus is a cruelty free alternative to animal leather. It also addresses the problems like the crop waste, animal cruelty, pollution, natural resources depletion and the like. Compositions of the present invention include processed Banana crop waste. Banana crops can be processed in a number of ways. In a preferred way, Banana crop waste is processed to obtain Banana pulp.

Compositions of the present invention for preparing vegan leather comprise of Banana pulp. Particularly, compositions for preparing vegan leather comprise of Banana pulp and at least one adhesive or binder. More particularly, compositions contain Banana pulp, one or more adhesives or binders and other additive such as a filler, softener / plasticizer, preservatives etc.

The Vegan leather prepared in accordance with the present invention comprises a backing material coated with a composition containing Banana pulp and other additives. Vegan leather prepared in accordance with the present invention comprises Banana pulp and adhesives and / or binders, fillers, softeners. plasticizers, colours / pigments, preservatives, lacquers, chemicals to prevent colour leakage^ water repellents.

Backing material comprises up to 20 % w/w of the final leather, preferably up to 10 % w/w of final leather, and most preferably up to 5 % w/w of the final leather.

Since compositions of the present invention are coated on the backing material, they are also referred to as coating compositions and coated backing material is called panels. Coating compositions comprise at least 85 % w/w, preferably at least 90 % w/w, more preferably at least 95 % w/w of the produced leather. Coating compositions are also called leather mixtures.

After coating of backing material with compositions of the present invention and plating which is done to enhance adhesion between backing material and coated compositions, leather is subjected to several finishing processes. Finishing of leather includes a series of steps to give buyers variety in the colours, embossing, shiny or matt finishes etc. and include top coating, surface treatment and adding chemicals to stop colour leakage and water proofing etc.

Upper coating contains colours / pigments, binders, preservatives, lacquers, chemicals to prevent colour leakage and water repellents together up to 5 % w/w, preferably, from 0.5 - 5 % w/w of final finished leather produced.

The Vegan leather prepared in accordance with the present invention comprises from 1 - 15 % w/w of backing material, colours / pigments, binders, lacquers, chemicals to prevent colour leakage and water repellents and 85 - 99 % w/w of coating composition containing Banana pulp and at least one adhesive / binder and optionally one or more of other additives such as fillers and softeners / plasticizers. Additionally, from 0.001 to 0.1 % w/w of preservatives are present when required.

In addition to Banana pulp, other ingredients of compositions to prepare vegan leather include at least one adhesive / binder and optionally other additives such as fillers, softeners / plasticizers, preservatives, colours etc. Filler provides structure and fullness to the leather. Starch is a preferred filler. Preferably starch is added in liquid form prepared as provided below. Starch from Tapioca, corn, potato and rice etc. can be used. Other fillers include polymer filler, waxes such as bees wax, paraffin wax, carnauba wax, cork powder, veg oil, wheat straw, rice husk etc.

Liquid Starch Preparation

• Grinding - The starch granules are first taken into a grinding machine to make powder form. It will take 5 min to make it fully powder form.

• Straining- the powder starch will be strained by a strainer.

• Boiling - Then the starch powder will be boiled for 30 minutes in the oven. Here the ratio is 20g starch powder will mix into 200 ml water and mix it properly and will take this for boiling.

• Straining- Then the liquid mixture will be strained again to make sure there is no thick starch present in the mixture. Otherwise, it may make a spot on the finished panel.

In an embodiment, starch is used as a filler. In another embodiment, polymer filler is one or more from Magnopal IPF, Magnopal BP, Magnopal Pure-A is employed.

The compositions to prepare Vegan Leather preferably contain at least one adhesive / binder. Adhesives and binders can be selected from natural source hereinafter natural adhesive or natural binder and chemical source hereinafter synthetic adhesive or synthetic binder. Adhesives ensure that there is no peeling off of the composition from backing material as well as it increases the intermolecular attraction between the compound molecules.

Preferred synthetic adhesives include Ethylene vinyl acetate, Polyvinyl acetate, Neoprene, plastic resin glue, epoxy glue etc. Preferred natural adhesives include Natural rubber, guar gum, gum Arabic, gum rosin etc. Natural adhesives also include some mixtures and glues prepared inhouse from arrowroot, gum rosin, gum Arabic, jackfruit, Guar gum, agar-agar powder etc. A preferred natural adhesive is jackfruit glue, arrowroot glue, corn-starch glue.

Amongst binders, preferred are Polyvinyl chloride, Polyurethane Binders, Acrylic Binders, Resin Binders, poly lactic acid, maleic anhydride, and Natural Binders made from Rubber and Starch. Binders are present in the compositions as well as in top colour coatings. Top coating binders include Protein binder, acrylic binder, PU binder and other types of thermoplastic Binder, non-thermoplastic binders, Butadiene Binder etc.

Plasticizers or softeners are added to obtain soft leather and include polyethylene glycol, polypropylene glycol, glycerol, isopropyl alcohol, epoxidized soybean, and other vegetable or fruit oils e.g., com, sunflower, palm etc.

Additionally, preservatives such as fungicides and bactericides, natural colours sourced from natural resources like charcoal black, beets, onion skins etc. can be added.

Banana pulp content of the compositions is from 40 - 70 % w/w, preferably from 50 - 70 % w/w, more preferably from 50 - 65 % w/w, and most preferably from 55 - 65 % w/w. Adhesive / Binder content is from 5 - 50 % w/w.

More than one adhesives or binders are also present depending on the requirements of final leather.

Additionally, from 5 - 35 % w/w of filler is present. When a soft leather is desired, 1 - 15 % w/w, preferably, 5 - 15% w/w of a softener / plasticizer such as polyethylene glycol can be added.

Further, other additives are present in the vegan leather such as preservatives, pigments, dyes, natural colours, binders for mixing with pigments etc.

Each of the compositions containing Banana pulp preferably contains at least 40 % w/w, more preferably at least 50 % w/w and most preferably from 55 - 65 % w/w of Banana pulp. Some of the Compositions of the present invention are as follows: i) 40 % w/w banana pulp + 30 % w/w adhesive + 30 % w/w filler; ii) 45 % w/w banana pulp + 30 % w/w adhesive + 25 % w/w filler; iii) 52 % w/w banana pulp + 25 % w/w adhesive + 23 % w/w filler; iv) 58 % w/w banana pulp + 21 % w/w adhesive + 21 % w/w filler; v) 50 % w/w banana pulp + 25 % w/w adhesive + 25 % w/w binder; vi) 58 % w/w banana pulp + 21 % w/w adhesive + 21 % w/w filler; vii) 50 % w/w banana pulp + 25 % w/w adhesive + 15 % w/w binder + 10 % w/w filler ; viii) 55 % w/w banana pulp + 25 % w/w adhesive + 15 % w/w binder + 5 % w/w filler; ix) 55 % w/w banana pulp + 26 % w/w adhesive + 14 % w/w binder + 5 % w/w filler; x) 60 % w/w banana pulp + 30 % w/w adhesive +10 % w/w filler; xi) 60 % w/w banana pulp + 30 % w/w adhesive +10 % w/w plasticizer / softener; xii) 60 % w/w banana pulp + 20 % w/w adhesive +10 % w/w filler + 10 % w/w plasticizer / softener; xiii) 65 % w/w banana pulp + 20 % w/w adhesive +5 % w/w filler + 10 % w/w plasticizer / softener; xiv) 65 % w/w banana pulp + 15 % w/w adhesive +10 % w/w binder + 10 % w/w plasticizer / softener; xv) 70 % w/w banana pulp + 20 % w/w adhesive + 5 % w/w filler; xvi) 60% w/w banana pulp + 20 % w/w binder 1 + 10% w/w binder 2 + 10% w/w binder 3 xvii) 50% w/w banana pulp + 10% w/w softener 1 + 15 % w/w binder 1 + 10% w/w binder 2 + 15% w/w softener 2; xviii) 50% w/w banana pulp + 30% w/w natural adhesive + 20% w/w binder; xix) 50% w/w banana pulp + 30% w/w synthetic adhesive + 20% w/w binder; xx) 50% w/w banana pulp + 30% w/w filler+ 20% w/w binder; xxi) 50% w/w banana pulp + 30% w/w Natural Rubber + 20% w/w Bio Poly Urethane; xxii) 50% w/w banana pulp + 30% w/w natural adhesive + 20% w/w binder; xxiii) 50% w/w banana pulp + 30% w/w synthetic adhesive + 20% w/w binder; xxiv) 50% w/w banana pulp + 30% w/w binder 1 + 20% w/w binder 2 xxv) 50% w/w banana pulp + 30% w/w Filler + 20% w/w binder xxvi) 60% w/w banana pulp + 20% w/w Filler + 10% w/w binder + 10% w/w wax softener xxvii) 50% w/w banana pulp + 30% w/w Filler + 20% w/w binder xxviii) 60% w/w banana pulp + 20% w/w Filler + 10% w/w binder + 10% w/w wax softener xxix) 50% w/w banana pulp + 15% w/w synthetic adhesive 1 + 20% w/w synthetic binder + 15% w/w synthetic adhesive 2; xxx) 50% w/w banana pulp + 15% w/w synthetic adhesive + 20% w/w Natural binder + 15 % w/w synthetic adhesive 2; xxxi) 60% w/w Banana pulp + 20 % w/w binder + 20% w/w plasticizer + 10% w/w Oil softener

Following specific embodiments represent the compositions of the present invention employing natural as well as synthetic adhesives and / binders, fillers, and softeners / plasticizers etc.

Neoprene, ethylene vinyl acetate, polyvinyl acetate, natural rubber, gum Arabic, gum rosin, agar-agar solution, arrowroot glue, solution are preferred adhesives.

Poly lactic acid, , polyvinyl chloride, maleic anhydride, polyurethane, Bio polyurethane, acrylic binder, resin binders, jackfruit glue, Arrowroot flour or Glue etc. act as binders.

Adhesives are used to cause adhesion between backing material and coating compositions so no material gets separated / peeled off. Binders act as adhesion bolsters. They enhance binding between backing material and compositions coated on backing materials and also enhance binding within the compositions. Starch from tapioca, rice, corn, potato, rice husk, cork filler, polymer filler magnopal IPF, Magnopal BP, Magnopal Pure-A are added as fillers to give fullness and structure. Additional fillers include waxes such as Bees wax, paraffin wax, veg oil, Agri-waste filler like rice husk, wheat straw etc.

Glycerol, isopropyl alcohol, polyethylene glycol, polypropylene glycol etc. are added as softeners /plasticizers which impart desired softness to the leather.

Following compositions are specifically produced and suitable backing materials are coated with these compositions to produce Vegan Leather.

A. 60% w/w banana pulp + 10 % w/w Poly Lactic Acid + 10% w/w PVC + 20% w/w Bio Poly Urethane

B. 50% w/w banana pulp + 10% w/w Isopropyl alcohol + 15 % w/w Poly Lactic Acid + 10% w/w Maleic anhydride + 15% w/w PVA

C. 50% w/w banana pulp + 30% w/w natural rubber + 20% w/w Polyvinyl Chloride

D. 50% w/w banana pulp + 30% w/w neoprene + 20% w/w Acrylic binder

E. 50% w/w banana pulp + 30% w/w Starch + 20% w/w Polyvinyl Chloride

F. 50% w/w banana pulp + 30% w/w Natural Rubber + 20% w/w Bio Poly Urethane

G. 50% w/w banana pulp + 30% w/w Gum Arabic solution + 20% w/wPVC

H. 50% w/w banana pulp + 30% w/w Polyvinyl acetate + 20% w/w Polyvinyl

Chloride

I. 50% w/w banana pulp + 30% w/w Poly Lactic Acid + 20% w/w Polyvinyl

Chloride

J. 50% w/w banana pulp + 30% w/w Cork Filler + 20% w/w Polyvinyl

Chloride

K. 60% w/w banana pulp + 10% w/w Cork Filler + 20% w/w Polyvinyl

Chloride + 10% w/w wax

L. 50% w/w banana pulp + 30% w/w Cork Filler + 20% w/w Polyvinyl

Chloride M. 60% w/w banana pulp + 20% w/w Cork Filler + 10% w/w Polyvinyl Chloride + 10% w/w wax

N. 50% w/w banana pulp + 15% w/w neoprene + 20% w/w Acrylic binder + 15% w/w Ethyl vinyl alcohol

O. 50% w/w banana pulp + 15% w/w neoprene + 20% w/w Resin binder + 15 % w/w Ethylene vinyl acetate

P. 60% w/w Banana pulp + 10% w/w Bio PU + 20% w/w PEG / glycerol as plasticizer + 10% w/w Oil

Q. 60% w/w Banana pulp + 30 % w/w polyvinyl acetate + 10 % w/w starch;

R. 55% w/w Banana pulp + 25 % w/w polyvinyl acetate + 20 % w/w Magnopal IPF as filler;

S. 58% w/w Banana pulp + 21 % w/w polyvinyl acetate + 21 % w/w bio polyurethane as binder ;

T. 55% w/w Banana pulp + 25 % w/w polyvinyl acetate + 20 % w/w Magnopal BP as filler;

U. 55% w/w Banana pulp + 26 % w/w polyvinyl acetate + 14 % w/w acrylic +5 % w/w starch as filler;

V. 60% w/w Banana pulp + 30 % w/w polyvinyl acetate + 10 % w/w PEG (as softener and plasticizer).

Following specific embodiments represent the compositions of the present invention employing natural adhesives such as natural rubber, jackfruit glue, Arrowroot Glue etc. a. 60% banana pulp + 20 % Starch + 10% Cork filler + 10% Natural Rubber b. 50% banana pulp + 10% Jackfruit Glue + 15 % Natural Rubber + 10% Gum Arabic + 15% Softener c. 50% banana pulp + 30% natural rubber + 20% Wheat Straw filler d. 50% banana pulp + 30% Starch + 20% Guar Gum e. 50% banana pulp + 30% Starch + 20% Veg oil f. 50% banana pulp + 30% Natural Rubber + 20% wheat straw powder g. 50% banana pulp + 30% Gum Arabic solution + 20% Citric acid h. 50% banana pulp + 30% Talcum powder + 20% Rice husk powder i. 50% banana pulp + 30% fruit wax + 20% Agar-agar solution j. 50% banana pulp + 30% Cork Filler + 20%Natural Rubber k. 60% banana pulp + 20% Cork Filler + 10% Natural Rubber + 10% wax l. 60% banana pulp + 20 % Starch + 10% Cork filler + 10% Guar Gum m. 60% Banana pulp + 30 % natural rubber + 10 % filler such as starch; n. 60% Banana pulp + 40 % natural rubber; o. 60% Banana pulp + 30 % natural rubber + 10 % natural adhesive; p. 60% Banana pulp + 30 % natural rubber + 10 % jackfruit glue; q. 60% Banana pulp + 30 % natural rubber + 10 % Arrowroot Glue;

In addition to various above compositions, dyes, pigments, colourants, binders for dyes and pigments and preservatives are part of these compositions and are added in amounts of up to 1 % w/w.

In a coating composition or leather mixture, banana pulp, adhesives / binders, fillers, softeners / plasticizers are present around up to 99 % w/w and dyes, pigments, binders for dyes and pigments and preservatives are present around up to 1 % w/w.

Processes for preparing compositions to prepare Vegan Leather and preparation of Vegan Leather therefrom

The compositions to prepare Vegan Leather are also termed as leather mixtures. A process of preparing compositions which are coated / sprayed on backing material to produce Vegan Leather has following steps: (CHANGE AS PER CLAIM) i) Preparing banana pulp; ii) Mixing banana pulp and adhesive / binder in a blender; iii) Optionally adding any additional adhesive and / or binder; or adding filler and / or softener and blending; iv) Mixing dyes / pigments / synthetic colour with a binder and adding the mixture to above blend while mixing.

Preparation of compositions of the present invention: Banana pulp and adhesive and / or binder are mixed in a blender. Mixing is continued for 1 hr. Such mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying. If additional adhesive / binder is to be added, it is added at this stage and mixed. Filler and / or softener is added and mixed well. Dyes / pigments / Synthetic Colour is mixed with preferably double the quantity of Binder and such mixture is added to the above composition while mixing. Additionally, preservatives are added if needed.

Preparation of Banana pulp comprises i) Preparing or obtaining banana stem cuttings; ii) Subjecting banana stem cuttings to alkali treatment; iii) Boiling banana stem cuttings in a suitable equipment or digester causing them to melt and form banana pulp; iv) Washing and straining pulp to wash out left over alkali; v) Grinding pulp and washing ground pulp; vi) Optionally bleaching the pulp and washing pulp to wash out bleaching agent.

Detailed Preparation of Banana pulp

Banana pulp is prepared by carrying out a series of process steps including alkali treatment, boiling, bleaching, ageing and intermittent washing in between these steps when needed. Bleaching is mainly followed for obtaining white or whitish shade and is an optional step when such shade is not required.

Banana stems are cut after trees give fruits. Upper surface of the stem is separated from the inner and middle portions of the stem as it is harder. Long cuttings of Inner and middle portions are collected and subjected to a banana shredder. Banana shredder is a stem cutting machine having sharp rolling blades inside. The shredder cuts the long cuttings of Inner and middle portions very quickly into small pieces of banana.

Banana stem cuttings / banana fibres are subjected to an alkali treatment during which 100 parts of Banana stem cuttings / banana fibres are mixed with around 1 - 2 parts of sodium sulfide and 2 - 3 parts of sodium hydroxide and 200 parts water and mixed. Other combinations of alkalis that result in a pH of 11-12, can also be employed like calcium hydroxide, aqueous ammonia, thiourea etc.

In the next step, the above mixture is subjected to boiling in a Digester. During boiling, stem cuttings are melted. The melted stem cuttings are subjected to grinding in a grinder for up to 15 - 30 mins., during which melted stem cuttings produce banana pulp. This pulp is brown coloured. It is washed with water to wash away alkali and strained in a strainer. After straining, pulp is subjected to grinding and then washing.

After washing the pulp is optionally subjected to bleaching. Bleaching is optional and done only when white / whitish leather is desired.

Bleaching process - 100 parts of pulp, around 6 - 7 parts of Bleaching powder (Calcium Oxychloride [Ca(OCl)2] and 200 parts of water are mixed. The mixture is kept overnight to lighten the original brown colour.

Bleaching chemicals like liquid bleach, hydrogen peroxide, sodium percarbonate, sodium perborate etc. are basic in nature and washing is necessary if bleaching is carried out to produce desired shade.

After bleaching the pulp, it is washed again. So, there involves 2-3 times intermittent washings in the process.

During the above processing steps, initial weight is reduced to almost 20 - 60 % w/w of the initial weight.

Preparation of Vegan Leather

A process of preparing Vegan leather comprises (As per the claim changes) i) Selecting and cutting backing material in suitable dimensions; ii) Preparing coating compositions; iii) Applying or spraying coating compositions on the backing material of suitable sizes to obtain panels; iv) Trowelling panels or spreading even the coated composition on panels; v) Drying panels under controlled temperature; vi) Plating dried panels; vii) Subjecting plated panels to colour spraying, drying and surface treatments comprising one or more of, milling, embossing and lacquering.

Additionally, the process of preparing Vegan Leather also comprises adding i) chemicals to prevent colour leakage and / or ii) water repellents during surface treatment.

Vegan leather from compositions of the present invention

The compositions of the present invention such as from compositions A to V or compositions a to q are applied in the form of coating on a backing material in the production of Vegan leather and hence the compositions are also termed as coating compositions. One or more coats can be applied on the backing layer one after the other.

A suitable backing material is selected from recycled plastic bottles, polyester, rayon, nylon, velvet, cotton fabric from a locally grown cotton, vegan fabrics made from banana, bamboo, jute, linen etc.

In an embodiment, backing material is obtained from recycled plastic bottles. Backing material can be cotton fabric from a locally grown cotton known for its suppleness and comfort. Organic cotton also enhances the biobased nature of the product. In another embodiment, backing material is linen.

Thickness ratio of backing material to coatings is usually from 1:2 to 1:10. In terms of weight, backing material is not more than 20 % w/w preferably not more than 10 % w/w of prepared leather.

The coated backing material is dried and subjected to a series of processes to convert it into vegan leather. In a Vegan Leather prepared according to the present invention, backing material or backing layer preferably comprises up to 10 % w/w, more preferably up to 5 % w/w and most preferably up to 2.5 % w/w. Coating compositions are preferably present in an amount of at least 90 % w/w, more preferably at least 95 % w/w and most preferably at least 98 - 99 % w/w.

Drying and other processes do not materially affect the constitution of coating compositions, backing material and therefore Vegan leather.

Preparation of Backing material

A suitable backing material is selected from recycled plastic bottles, polyester, rayon, nylon, velvet, cotton fabric from a locally grown cotton, vegan fabrics made from banana, bamboo, jute, linen etc..

Backing material is cut into various desired sizes as per the requirements and available drying infrastructure. In an embodiment, preferably a size of 8 ft X 10 ft has been employed. In another embodiment a smaller size of 27 inches X 40 inches has been employed.

Preferably, cotton fabric is selected and cut into a size of 27 X 40 square inches. Fabric is ironed if it is creased or folded.

Preparation of Vegan leather

In a first step, backing material is cut into desired dimensions.

In the second step, the backing material is placed on a spraying table. Then 2 coats of any of the compositions are sequentially sprayed on the backing material using a spray gun to produce panels. Panel is backing material coated with compositions / leather mixtures. After first coat, panel is subjected to drying.

For various approximate thickness, following coating compositions are preferably applied.

Around 1.7 kg of compound is needed for one 27 by 40 inches fabric for overall 1mm thickness. Backing material of larger size such as 8 X 10 sq. feet or larger size can be employed.

After spraying, panels are trowelled in which even spreading of coated material is done.

Next step is drying. After trowelling the panels, they are kept in drying racks and are subjected to drying at a specific temperature. Drying temperature is controlled and not allowed to exceed 60°C as it may burn upper soft portion of the coating. Panels are dried for at least 24 hrs., preferably for 48 hrs.

Further, the dried coated panels are subjected sequentially to plating, colour spraying, embossing, and lacquering. Drying is needed after each of the steps involving colour spraying, embossing, and lacquering.

These steps are described as follows:

Plating - Each panel is subjected to specific temperature and pressure and time. Preferably, pressure of from 200 - 300 MPa or Bar, preferably 250 MPa or Bar at 80°C for 1.5 sec. at a second in a hydraulic press machine. Plating softens the upper surface and increases the bonding between fabric /backing material and the layers of coatings.

Further, leather is subjected through various finishing processes.

Finishing

Finishing of leather includes a series of steps to give buyers variety in the colours, embossing, shiny or matt finishes etc. and include spray painting, surface treatment and adding chemicals to stop colour leakage and water proofing etc...

Finishing materials are up to 10 % w/w, preferably up to 5 % w/w of the leather, more preferably from 2% w/w to 4% w/w of the all coating and contains colours, binders, lacquers, and water resistant / water repellent coatings. Eacquers include polyurethane lacquers, dyes lacquers, resin based lacquers, different types of nitrocellulose lacquers, Acrylic Lacquers, and also, water based silicone emulsions etc...

There are a variety of colours which can be employed in the compositions. Some of them are dyes, pigments & natural colours (made from organic compounds like coal tars, some petrochemicals i.e., benzene, toluene, xylene, oil & inorganic compounds like oxidation of metals i.e., titanium, iron etc).

Some of the colours are mixed with binders. There is a huge variety in binders. Most commonly, acrylic binders, polyurethane binders, Resin binders etc. are employed.

There is an alternative option of using 100 % w/w bio based binders. Here the binder is made from Natural Rubber and Starch [the process of starch mixture has already been mentioned in the above section] (1:3) or (1:4) or (1:5) or (1:6)

Embossing includes NDM embossed, PDM embossed, YDM embossed, Croco embossed, Printing, Foiling and other types.

Colour Spraying / Spray coating

First coat of colour- After plating the next step is colour coating. Here the Synthetic pigments that are made by some organic and inorganic compounds are used for coating. The pigments used in colour coating are absolutely sustainable and eco-friendly. The pigments are mixed with a binder in a ratio from 1:5 to 1:15, preferably in 1:10 ratio.

Surface treatment

After one coat of spray, the panels are kept for drying for 24 hours for fixation of colour. Next step is surface treatment and includes milling and embossing.

Milling After colour coating and drying, the panels are subjected to a Milling process to increase the softness. It is a drum operation where the panels are revolved in the drum. Due to this operation the upper surface of the material gets creasing effects like leather finishes.

Embossing

It is important to give vegan leather a look of leather. To emboss the upper surface there are many types of plates in the leather industry. Embossing imparts a raised pattern and enhances the look of the leather. There are many plates available in the leather industry. A suitable plate is selected and embossing is done at specific temperature and pressure.

After Embossing, the spray coating step is usually repeated if colours fade during embossing.

Top coating treatment

The pigments are mixed with a suitable binder in specific ratio from 1:5 to 1:15 preferably, 1:10 and sprayed on the panel. After colour coating, panels are dried for 24 hrs, and then if desired, a second coating is done followed by drying.

Before lacquering the panel, it is mandatory to ensure the colour of the upper surface has dried properly. So, a minimum 24 hours of drying time is needed.

Next step is Lacquering.

Lacquering is done to give desired finish to the prepared leather. Lacquering is done using various types of lacquers including but not limited to nitrocellulose based or cellulose acetate butyrate based which imparts gloss to the leather.

A nitrocellulose based lacquer is diluted using water. Additionally, a feeler that modifies touch and feel of a leather such as plant based or silicon based coating emulsion having properties like silicon coating is added to impart smooth touch. 49 % w/w shine lacquer is diluted with 49 % w/w with water and 2 % w/w plant based or silicon based coating emulsion similar properties like silicon coating is mixed in it to provide lacquer suspension. Lacquer suspension is applied as top coat on the prepared leather.

Drying is essential after colour spraying, before and after lacquering. When colour spraying is done multiple times, drying between each spray is essential. Minimum 24 hrs. drying time is used after each colour spraying and before and after Lacquering.

The Vegan leather prepared in accordance with the present invention comprises a backing material coated with a compositions containing Banana pulp and other additives such as adhesives, binders, fillers, softeners / plasticizers, colours / pigments, preservatives, lacquers, chemicals to prevent colour leakage and water repellents. Backing material comprises up to 20 % w/w, preferably up to 15 % w/w, more preferably up to 10 % w/w of the final leather, most preferably up to 5 % w/w of final leather. In most embodiments, backing material comprises preferably up to 2.5 % w/w of the final leather.

Since compositions of the present invention are coated on the backing material, they are also referred to as coating compositions. Coating compositions or leather mixture along with top coatings comprise at least 85 % w/w, preferably at least 90 % w/w, more preferably at least 95 % w/w of the produced leather.

During finishing, colours / pigments, binders, preservatives, lacquers, chemicals to prevent colour leakage and water repellents together not more than 5 % w/w are added.

The Vegan leather prepared in accordance with the present invention comprises 1 - 15 % w/w of backing material, colours / pigments, binders, lacquers, chemicals to prevent colour leakage and water repellents and 85 - 99 % w/w of coating composition containing Banana pulp and one or more of additives such as adhesives, binders, fillers, softeners / plasticizers. Additionally, from 0.001 to 0.1 % w/w preservatives are present when required. Depending on the nature of the additives, the compositions are divided into those containing synthetic adhesives and natural adhesives.

Arriving at the suitable compositions which can produce Vegan Leather was a difficult task and inventors faced several challenges.

These challenges include i) Colour Bleeding Problem; ii) Creasing Problem; iii) moisture retention problem or hygroscopic contents; iv) Cracking Problem; v) formation of air bubbles; vi) fungal growth; vii) Upper Surface peeling; viii) durability problem.

Additionally, inventors faced few process related and machine related challenges.

Colour Bleeding

Colour Bleeding was one of the major problems faced. To solve the same, following trials have been taken:

Used various type of pigments, dyes (different molecular size, different composition, metal free) were tried. Dyes are chemicals with smaller molecular size than pigments, and dyes are easily soluble while pigments are partially insoluble in Various types of binders (acrylic, resin, PU etc.) were tried, that were mixed with the colour in various concentrations;

Various types of lacquers were used to coat the top surface (NC based, Acetate based, cellulose acetate butyrate (CAB) lacquer etc. from different sources) were tried;

Top coating was made water repellent to prevent colour bleeding through ( silica coating, wax finish etc).

Creasing Problem This problem was one of the major problems found in vegan leather. Because vegan leather does not contain collagen fibre like animal leather, it does not have the same properties of elasticity and fullness. Either vegan leather is made of PU, PVC, rubber or cellulosic materials. So, it is hard to make the same fullness, feel like animal leather.

To solve the same, following trials are taken, various soft backings (cotton, polyester etc.) were tried; filler material is added to enhance the softness ( wax, starch, veg oil, agri-waste filler like rice husk, wheat straw, cork powder etc).

Moisture Problem

There are some chemicals which are hygroscopic in nature. They absorb moisture from the environment. This moisture is retained on the upper surface and the finishing chemicals cannot bind with the base material.

To solve the same, following trials are taken.

Treated the Banana pulp with Silane.

Added metal Silicate powder like magnesium silicate in the composition in 0.5% w/w concentrations which is hydrophobic in nature; Drying is done at high temperature;

Used dehumidifier;

Pulp is dried entirely in sun and stored for 2 weeks before being rehydrated again.

Cracking Problem

If the base compound is very hard or the upper surface is rough or the upper coating is rough or the upper coating does not bind with the base surface it causes cracking. To solve the same, following trials are taken.

Softener / plasticizers are employed whenever required such as veg oil, soft filler etc.

Different upper coatings ( bio-based PU, Acrylic binder etc) are tried;

Softener is also employed in the upper coating like (silicon solution, crunchy wax etc). Bubble Problem

This is particularly observed when natural rubber was used in the composition, or the material was made through a single extremely thick layer, instead of thinner multilayers. Sometimes the natural rubber creates an air bubble in the composition when it is heated by a little higher temperature like 80 degrees or mixing time. Sometimes air bubbles are created on the upper surface for not mixing the composition properly or during spraying from the gun.

To solve the same, following trials are taken.

Mixing time is increased;

Mixing is done in a suitable blender;

Added defoaming agent ( hydrogen peroxide, Sodium percarbonate, peracetic acid, sodium perborate);

Adhesives with good binding property are employed.

Fungus Problem

Fungus growth is observed after five to six months in the panels. To avoid bacteria and fungal activity in the panel, spraying Antifungal, Antibacterial was tried. Most of the Vegan Leathers now employ a suitable preservative.

Upper Surface peeling

Due to the moisture, the upper surface can peel off easily. Because the upper coating does not bind on the base compound if there is moisture. So, the base material should be moist free.

To solve the same, following trials are taken.

Treated the pulp with Silane;

Added metal Silicate powder in the base compound which is hydrophobic in nature; Drying in high temperature;

Used dehumidifier;

Pulp is dried and hydrated again while making the compositions. Durability Problem

The most important thing is durability of a material, initially the durability was not so good due to many reasons like Fungus, Peeling problem, cracking problem, moisture problem. So, the material went through a lot of trials to get this perfection.

Initial Procedure problems

Alkali Treatment

Initially developed process did not include alkali treatment. It was done only by boiling and mixing. So, the panel made from that pulp is much harder. So, chemicals that can dissolve the stem into a pulp homogenously were used such as some hydroxides like sodium hydroxide and sulphide compounds like sodium sulphide along with sodium hypochlorite that are finalized for alkali treatment.

Adhesives

The adhesive used in previous conditions made the panel harder and less eco- friendly. So, there are a lot of trials to choose the appropriate adhesives.

Natural additives

It was hard to find 100% w/w natural adhesive, so it was decided to create a natural adhesives that is made from arrowroot, gum rosin, gum Arabic, jackfruit glue etc.

Filler

There are many options for a filler. To find a good filler, many trials are undertaken.

Inventors had undertaken many trials in various concentrations like starch, wax, cork powder, polymer filler, veg oil, rice husk, wheat straw, etc.

Machinery problems Initially all the machinery steps were done manually due to small scale. So, there were always many problems like the thickness variation , the compound consistency variation, colour variation . This was fixed by specific measurement of applied coating, constant measuring of variation after each lot to provide feedback and improve consistency.

Accordingly, following machinery is added now to eliminate manual variation:

Roller coating machine

Hydraulic press

Spraying booth with spray gun and compressor

Milling drum

Digester

Grinding Machine

Dehumidifier

Hot air oven

Finally, the inventors arrived at the compositions of the present invention and a good quality Vegan Leather is produced using the same.

Another problem was on panel softness variation due to hand milling. The molisa and milling steps through machinery were added which can be effectively done.

Producing 100% w/w natural Vegan Leather

Usually, marketed Vegan leathers contain at least 10% w/w of Polyurethane or polyvinyl chloride etc. It was very much challenging to make leather which has zero plastic and is made of 100% w/w natural materials. In the present invention, inventors carried out several trials to produce 100 % w/w natural, vegan, durable and soft leather suitable for several goods or products.

To solve the same, following trials are taken.

Natural Adhesive are sourced like natural rubber, gum rosin, gum Arabic, jackfruit glue, arrowroot glue, agar-agar solution, banyan sap glue, com starch adhesive etc. Natural Adhesive are prepared inhouse from many different sources like jackfruit, arrowroot, gum rosin, gum-arabic, banyan sap, com starch, guar gum etc. Natural Binders are used such as Starch from rice or tapioca with a great binding capacity and arrowroot and rubber.

Natural fillers such as starch from tapioca, rice, corn, cork filler, rice husk, wheat straw, talcum powder etc. are employed.

Natural softener such as veg oil, fruit oil, citric acid, fruit waxes etc.

Natural colours are employed such as colours from charcoal black, beets, onion skins etc.

Following examples without limiting the scope of the invention provide, i) preparation of Banana pulp (example 1) ii) preparation of compositions of the present invention containing from 40 - 70 % Banana pulp (example 2); iii) preparation of Vegan Leather (example 3).

Figures 1 and 3 also provide details of all process steps followed in manufacturing of Vegan Leather according to the present invention.

Referring to FIG. 1, the plant-based vegan method 100 includes a step 102 of pulp extraction. At this step, the pulp from the raw banana stem is extracted. As mentioned above, after the banana plant bears fruit, the stem becomes redundant. The present method 100 can utilize this banana stem for pulp extraction, at step 102. For pulp extraction, the banana stem is cut into fine pieces and boiled with chemicals, such as including and not limited to NaOH, Na2S, NaHClO and common salt. Thereafter, the chemically treated pulp is drained and rinsed. It may be apparent to a person skilled in the art that the pulp extraction from banana stem may implement any conventionally used methods and processes, without deviating from the meaning and scope of the present invention.

At a step 104, tapioca starch is powdered and then boiled with water to reach a jelly like consistency. It may be apparent to a person skilled in the art that the present plant-based vegan method 100 may use any other starch extracted from the plants, without deviating from the meaning and scope of the present invention.

The plant-based vegan method 100 also includes a step 106 for creating a leather mixture. The step 106 further includes mixing the pulp obtained in the step 102 and the tapioca obtained in the step 104 with additional chemicals (such as including and not limited to adhesives, PU, polyvinyl acetate, and other plasticizers) to then create a leather mixture.

Further, the method includes a step 108 of spraying / pouring or screen printing the leather mixture obtained in the step 106 onto a fabric backing. The fabric backing can be for example made from recycled PET bottles. The sprayed leather mixture in the step 108 is then air dried, at a step 110.

The air-dried leather material is then spray painted for smooth finishing, at a step 112. The spray painting includes coating the leather material with a smooth material, as a finishing process for the material.

At a step 114, the spray-painted leather undergoes sub-processes like plating and pressing.

In an embodiment, this sub- process of plating and pressing includes putting the leather under a hot plate and pressed. Plating is a finishing process that can be very useful as it makes leather more uniform and smoother, and at the same time more lucid.

Further, at a step 116, the pressed leather material at step 114, undergoes a surface treatment process, which includes and is not limited to creasing the leather material for a creased look, adding chemicals to improve flexibility, water resistance, fire resistance.

It may be apparent to a person skilled in the art that the present plant-based vegan method 100 may use any suitable and conventionally available chemicals for improving the flexibility of the leather material, without deviating from the meaning and scope of the present invention. It may be apparent to a person skilled in the art that the present plant-based vegan method 100 may use any other conventionally used surface treatment processes also at step 116, without deviating from the meaning and scope of the present invention.

Further, in an embodiment, the method 100 may also include a step 118 of repeating the spray-painting process to further finish the material. The step 118 of repeating the spray painting may be optional step, and can be implemented as and when needed.

Further, the method 100 includes a step 120 where some suitable chemicals can be added to stop color leakage from the finished leather material. It may be apparent to a person skilled in the art that the present plant-based vegan method 100 may use any suitable and conventionally available chemicals for stopping the color leakage from the finished leather material, without deviating from the meaning and scope of the present invention.

Example 1 - Preparation of Banana pulp

Banana stems are cut after trees give fruits. Upper surface of the stem is separated from the inner and middle portions of the stem as it is harder. Long cuttings of inner and middle portions are collected and subjected to a banana shredder. Banana shredder is a stem cutting machine having sharp rolling blades inside. The shredder cuts the long cuttings of inner and middle portions very quickly into small pieces of banana.

Banana stem cuttings / banana fibres are subjected to an alkali treatment during which 100 parts of Banana stem cuttings / banana fibres are mixed with 2.6 parts Sodium Hydroxide, 1.6 parts Sodium Sulphide and 200 parts water and mixed.

In the next step, the above mixture is subjected to boiling in a Digester for 45 minutes. During boiling, stem cuttings are melted. The melted stem cuttings are subjected to grinding in a grinder for 15 mins., during which melted stem cuttings produce banana pulp. This pulp is brown coloured. It is washed with water to wash away alkali and strained in a strainer. After straining, pulp is subjected to grinding and then washing.

After washing the pulp is optionally subjected to bleaching. Bleaching is optional and done only when white / whitish leather is desired.

Bleaching process - Weighed 100 parts of pulp and added 6.6 parts of Bleaching powder (Calcium Oxychloride [Ca(OCl)2] and 200 parts of water and are mixed. The mixture is kept overnight to lighten the original brown colour. Bleaching chemicals like liquid bleach, hydrogen peroxide, sodium percarbonate, sodium perborate etc. are basic in nature and washing is necessary if bleaching is carried out to produce desired shade.

After bleaching the pulp, it is washed again. So, there involves 2-3 times intermittent washings in the process.

During the above processing steps, initial weight is reduced to almost 25 % w/w of the initial weight.

Example 2 - Preparation of compositions A to W of the present invention:

A. 60% w/w banana pulp + 20 % w/w Poly Lactic Acid + 10% w/w PVC + 10% w/w Bio Poly Urethane

Poly lactic acid (PLA) is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr with. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Polyvinyl chloride (PVC) and polyurethane (PU) in liquid form are added and mixed for another 15 minutes. PVC and PU mainly work in this compound as a filler to give fullness and structure to the leather.

99 % w/w of the above mixture and up to 1 % w/w of mixture of Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing.

Because of moisture release tendency of the Banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added.

B. 50% w/w banana pulp + 10% w/w IPA + 15 % w/w PLA + 10% w/w Maleic anhydrous + 15 % w/w glycerol

10% w/w IPA and 15% w/w PLA are mixed with 50% w/w banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr with mixing compound elements one by one. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

10% w/w Maleic anhydride and 15% w/w glycerol are added and mixed for another 15 minutes. Glycerol mainly works in this compound as a filler to give fullness and structure to the leather.

99 % w/w of the above mixture and up to 1 % w/w of mixture of Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing.

Because of the moisture release tendency of the banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added.

C. 50% w/w banana pulp + 30% w/w natural rubber + 20% w/w Polyvinyl Chloride

30% w/w Natural Rubber is mixed with 50% w/w Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr with mixing compound elements one by one. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

20% w/w PVC in liquid form is added and mixed for another 15 minutes. PVC mainly works in this compound as a filler to give fullness and structure to the leather.

99 % w/w of the above mixture and up to 1 % w/w of mixture of Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing.

Because of the moisture release tendency of the Banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added.

D. 50% w/w banana pulp + 30% w/w neoprene + 20% w/w acrylic binder 30% w/w Neoprene is mixed with 50% w/w Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr with mixing compound elements one by one. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

20% w/w acrylic binder in liquid form is added and mixed for another 15 minutes. Acrylic binder mainly works in this compound as a filler to give fullness and structure to the leather.

99 % w/w of the above mixture and up to 1 % w/w of mixture of Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing. Because of the moisture release tendency of the Banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added.

E. 50% w/w banana pulp + 30% w/w Starch + 20% w/w Polyvinyl Chloride

20% w/w PVC is mixed with 50% w/w Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr with mixing compound elements one by one. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

30% w/w starch in liquid form is added and mixed for another 15 minutes. Starch mainly works in this compound as a filler to give fullness and structure to the leather.

99 % w/w of the above mixture and up to 1 % w/w of mixture of Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing.

Because of the moisture absorption capacity of starch and moisture release tendency of the Banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added. 99. 50% w/w banana pulp + 30% w/w Natural Rubber + 20% w/w Bio Poly Urethane

30% w/w Natural Rubber is mixed with 50% w/w Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

20 % w/w Bio PU in liquid form is added and mixed for another 15 minutes. Bio PU mainly works in this compound as a filler to give fullness and structure to the leather.

99 % w/w of the above mixture and up to 1 % w/w of mixture of Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing.

Because of the moisture release tendency of the Banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added.

G. 50% w/w banana pulp + 30% w/w Gum Arabic solution + 20% w/w PVC

20% w/w PVC is mixed with 50% w/w Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr with mixing compound elements one by one. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

30% w/w Gum Arabic solution in liquid form is added and mixed for another 15 minutes.

99 % w/w of the above mixture and up to 1 % w/w of mixture of Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing.

Because of the moisture release tendency of the Banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added. The introduction of a 30% w/w Gum Arabic solution further enriches the formulation. This addition plays a crucial role in enhancing the adhesive capabilities of the mixture. Gum Arabic’s colloidal properties, when solubilized, create a viscous solution that contributes to the cohesion of the composition and its adhesion with backing material. Its natural origin aligns with the increasing demand for eco-friendly adhesive alternatives.

Complementing the natural elements, 20% w/w PVC is incorporated into the mixture. PVC’s synthetic nature imparts durability and resilience to the formulation, elevating its mechanical properties. This synergy of natural and synthetic constituents is orchestrated to yield a balanced composition that bridges the gap between sustainability and performance.

In summary, the innovation lies in the meticulous combination of 50% w/w banana pulp, 30% w/w Gum Arabic solution, and 20% w/w PVC. This fusion embodies the advantages of each component, resulting in a well-rounded adhesive composition that merges the strengths of natural binding, colloidal adhesion enhancement, and synthetic durability. The final composition is poised to cater to a diverse range of applications, presenting a promising direction in adhesive technology.

H. 50% w/w banana pulp + 30% w/w PVA + 20% w/w PVC

The composition comprises 50% w/w banana pulp, 30% w/w Polyvinyl Acetate (PVA), and 20% w/w Polyvinyl Chloride (PVC).

30% w/w Polyvinyl Acetate is mixed with 50% w/w Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr with mixing compound elements one by one. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Polyvinyl chloride (PVC) in liquid form is added and mixed for another 15 minutes. 99 % w/w of the above mixture and up to 1 % w/w of mixture of Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing. Because of the moisture release tendency of the Banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added. This innovative formulation underscores the combination of 50% w/w banana pulp, 30% w/w Polyvinyl Acetate (PVA), and 20% w/w Polyvinyl Chloride (PVC) to create a composition with multifaceted attributes. The substantial inclusion of banana pulp as the primary component contributes both natural adhesion properties and environmental sustainability to the mixture. Banana pulp's inherent adhesiveness, stemming from its organic composition, lays the foundation for a strong bonding capability. The introduction of 30% w/w PVA amplifies the adhesive potential of the composition. PVA, renowned for its versatility and adhesive qualities, enhances the cohesion between the components, further bolstering the adhesion properties of the mixture. Balancing the equation, 20% w/w PVC adds a dimension of durability and resilience to the composition. PVC's synthetic nature imparts mechanical strength and longevity to the adhesive, ensuring its effectiveness over time. This meticulously composed mixture not only taps into the innate adhesion strengths of natural elements but also integrates synthetic durability for a well-rounded solution poised to cater to a spectrum of applications.

I. 50% w/w Banana Pulp + 30% w/w Poly Lactic Acid + 20% w/w PVC

Poly Lactic Acid is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr with. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Polyvinyl chloride (PVC) in liquid form is added and mixed for another 15 minutes. 99 % w/w of the above mixture and up to 1 % w/w of mixture of Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing.

This formulation epitomizes the synergy between 50% w/w banana pulp, 30% w/w Polylactic Acid (PLA), and 20% w/w Polyvinyl Chloride (PVC), yielding a composition designed to bridge the realms of sustainability and performance. The substantial incorporation of banana pulp, constituting half of the composite, infuses the mixture with inherent natural adhesion properties. The eco-friendly attributes of banana pulp align with the growing demand for sustainable materials in adhesive applications. The introduction of 30% w/w PLA, a biodegradable polymer derived from renewable resources, amplifies the environmentally conscious profile of the composite. PLA's adhesive capabilities, combined with its biodegradability, contribute to the cohesive strength of the mixture. Balancing the equation, 20% w/w PVC introduces a synthetic dimension that enhances the composite's mechanical integrity and resilience. PVC's robustness augments the durability of the adhesive, ensuring its stability under varying conditions. In amalgamating these components, this composition not only harnesses the natural adhesive strengths of banana pulp and the ecological benefits of PLA but also integrates the durability of PVC, presenting a well-rounded adhesive solution poised to address contemporary sustainability and performance requirements.

J. 50% w/w Banana Pulp + 30% w/w Cork Filler + 20% w/w PVC

30% w/w Cork filler is mixed with 50% w/w Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr with mixing compound elements one by one. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Polyvinyl chloride (PVC) in liquid form is added and mixed for another 15 minutes. 99 % w/w of the above mixture and up to 1 % w/w of mixture of Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing.

Because of the moisture release tendency of the Banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added. This distinctive formulation brings together 50% w/w banana pulp, 30% w/w cork filler, and 20% w/w Polyvinyl Chloride (PVC) to create an adhesive composite with a well-balanced blend of natural and synthetic components. The significant inclusion of banana pulp, constituting half of the composition, contributes inherent adhesion properties along with a touch of environmental sustainability. Banana pulp's natural adhesiveness serves as a foundation for strong bonding capabilities within the mixture. The introduction of 30% w/w cork filler enhances the texture and resilience of the composite. The porous nature of cork functions as an effective filler, promoting cohesion and structural strength in the adhesive. The balance is achieved with the incorporation of 20% w/w PVC, which imparts mechanical strength and endurance to the composition. The synthetic properties of PVC ensure the adhesive's stability and longevity, making it effective over time. In harmony, these elements create a cohesive and well-rounded adhesive composite that capitalizes on the adhesion strengths of natural components while integrating the durability of synthetic materials.

K. 60% w/w Banana Pulp + 20% w/w Cork Filler + 10% w/w PVC + 10% w/w Wax

20% w/w Cork filler is mixed with 60% w/w Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr with mixing compound elements one by one. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Wax is melted. Polyvinyl chloride (PVC) in liquid form and Wax in molten form are added and mixed for another 15 minutes.

99 % w/w of the above mixture and up to 1 % w/w of mixture of Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing.

Because of the moisture release tendency of the Banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added.

This innovative formulation artfully combines 60% w/w banana pulp, 20% w/w cork filler, 10% w/w Polyvinyl Chloride (PVC), and 10% w/w wax, creating an adhesive composition that blends diverse attributes for a multifaceted solution. The prominent presence of banana pulp, constituting a majority of the composition, introduces inherent adhesion strengths coupled with an environmental consciousness. The natural adhesive qualities of banana pulp, paired with its biodegradability, form a strong foundation for robust bonding capabilities within the adhesive. The incorporation of 20% w/w cork filler further enriches the composition's texture and resilience. Cork's porous and flexible structure contributes to the overall cohesion and mechanical integrity of the adhesive. The inclusion of 10% w/w PVC provides the composition with mechanical durability and longevity. PVC's synthetic attributes enhance the adhesive's stability, ensuring its effectiveness in various conditions. To add a layer of flexibility and pliability, 10% w/w wax is introduced. This component contributes to the adhesive's malleability, allowing it to adapt to different surfaces and contours. In this orchestrated union, the composition draws from the natural adhesive strengths of banana pulp, the reinforcing properties of cork and PVC, and the flexibility offered by wax, resulting in a versatile adhesive solution poised to meet diverse industrial demands.

L: 5(1% w/w Banana Pulp + 30% w/w Cork Filler + 20% w/w PVC

30% w/w Cork filler is mixed with 50% w/w Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr with mixing compound elements one by one. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Polyvinyl chloride (PVC) in liquid form is added and mixed for another 15 minutes. 99 % w/w of the above mixture and up to 1 % w/w of mixture of Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing.

Because of the moisture release tendency of the Banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added.

The innovative blend of 50% w/w banana pulp, 30% w/w cork filler, and 20% w/w Polyvinyl Chloride (PVC) forms a composite that uniquely fuses natural and synthetic elements. The substantial incorporation of banana pulp contributes both eco-friendliness and inherent adhesion properties to the composite. T'his natural component adds an element of biodegradability and sustainability to the adhesive. aligning with environmentally conscious demands. The introduction of 30% w/w cork filler amplifies the composite’s texture and resilience. Cork’s porous nature serves as an effective filler, enhancing the overall structural integrity and adhesive properties of the mixture. Balancing the equation, 20% w/w PVC provides the composite with mechanical strength and durability. PVC’s synthetic characteristics offer stability and longevity to the adhesive, ensuring its effectiveness over time. In synergy, these elements create a cohesive blend that draws from the strengths of each constituent, resulting in an adhesive composition with attributes poised to meet a range of industry requirements.

M: 60% w/w Banana Pulp + 20%' w/w Cork Filler + 10% w/w PVC + 10% w/w Wax

20% w/w Cork filler is mixed with 60% w/w Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr with mixing compound elements one by one. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Wax is melted. Polyvinyl chloride (PVC) in liquid form and Wax in molten form are added and mixed for another 15 minutes.

99 % w/w of the above mixture and up to 1 % w/w of mixture of Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing.

Because of the moisture release tendency of the Banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added.

This composition strategically combines 60% w/w banana pulp, 20% w/w cork filler, !()% w/w Polyvinyl Chloride (PVC), and 10% w/w wax to engineer an adhesive composite with a nuanced balance of properties. The substantial presence of banana pulp as the primary component introduces inherent adhesion strengths and environmental sustainability to the mixture. Banana pulp’s natural adhesive qualities, combined with its biodegradability, form a foundation for strong bonding capabilities. The incorporation of 20% w/w cork filler enhances the composite's texture and resilience. The cork’s unique porous structure contributes to the overall cohesion and structural robustness of the adhesive. Introducing 10% w/w PVC adds a synthetic element that imparts mechanical durability and longevity. PVC's strength augments the composite's resilience, ensuring its stability under varying conditions. Further, the inclusion of 10% w/w wax contributes to the adhesive's pliability and flexibility. This synergistic amalgamation blends the eco -friendly and adhesive attributes of banana pulp with the reinforcement of cork, PVC, and wax, resulting in a versatile adhesive solution poised to address diverse industry needs. w/w Banana Pulp + .1.5% w/w Neoprene + 20%; w/w Aerylie Binder +

15% w/w EVA

30% w/w Neoprene and 15 % w/w ethylene vinyl acetate are mixed with 50% w/w Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr with mixing compound elements one by one. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

20% w/w Acrylic binder in liquid form is added and mixed for another 15 minutes. Acrylic binder mainly works in this compound as a filler to give fullness and structure to the leather.

99 % w/w of the above mixture and up to 1 % w/w of mixture of Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing. Because of the moisture release tendency of the Banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added.

The innovative blend comprising 50% w/w banana pulp, 15% w/w neoprene, 20% w/w Acrylic Binder, and 15% w/w Ethylene Vinyl Acetate (EVA) brings together diverse elements to create an adhesive composite that stands at the crossroads of natural and synthetic characteristics. The prominent inclusion of banana pulp introduces inherent adhesion properties and ecological consciousness to the blend. This natural component offers biodegradability and environmental sustainability, aligning with the growing demand for eco-friendly solutions. Incorporating 15% w/w neoprene enhances the composite's flexibility and resilience. Neoprene's elastomeric nature contributes to the adhesive's adaptability to varying conditions. The introduction of 20% w/w Acrylic Binder enhances adhesion and cohesion. Acrylic binders are known for their strong bonding capabilities, fortifying the adhesive's overall performance. The addition of 15% w/w EVA adds a synthetic dimension that imparts mechanical stability and durability to the mixture. EVA's properties ensure the composite's longevity and robustness over time. In harmony, these components form a composite that merges the natural adhesion strengths of banana pulp, the flexibility of neoprene, the binding capabilities of acrylic, and the durability of EVA, yielding an adhesive solution tailored to diverse applications.

O. 50% w/w Banana Pulp + 15% w/w Neoprene + 20% w/w Resin Binder + 15% w/w EVA

15% w/w Neoprene and 15 % w/w ethylene vinyl acetate are mixed with 50% w/w Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr with mixing compound elements one by one. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

20% w/w Resin binder in liquid form is added and mixed for another 15 minutes. Acrylic binder mainly works in this compound as a filler to give fullness and structure to the leather.

99 % w/w of the above mixture and up to 1 % w/w of mixture of Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing. Because of the moisture release tendency of the Banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added.

The inventive formulation featuring 50% w/w banana pulp, 15% w/w neoprene, 20% w/w Resin Binder, and 15% w/w Ethylene Vinyl Acetate (EVA) showcases a strategic combination of natural and synthetic elements. The substantial integration of banana pulp imparts inherent adhesion strengths and environmental sustainability to the composite. This natural component delivers both robust bonding capabilities and biodegradability, aligning with eco-friendly standards. The inclusion of 15% w/w neoprene augments the adhesive's elasticity and resilience. Neoprene's flexible nature ensures the adhesive can adapt to various conditions while maintaining cohesion. Incorporating 20% w/w Resin Binder bolsters the adhesive's binding properties and structural integrity. Resin binders are recognized for their robust adhesion characteristics, enhancing the overall performance of the mixture. The introduction of 15% w/w EVA introduces synthetic durability and mechanical stability to the composite. EVA's attributes contribute to the adhesive's lasting strength and reliability. In unison, these constituents create a composite that synergistically leverages the natural adhesion properties of banana pulp, the flexibility of neoprene, the binding efficacy of resin, and the durability of EVA, yielding a versatile adhesive solution suitable for an array of applications.

P. 60% w/w Banana pulp + 10% w/w Bio PU + 20% w/w Plasticizer + 10% w/w Oil

20 % w/w plasticizer selected from Glycerol or PEG and 10 % w/w oil are mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Bio polyurethane (Bio PU) in liquid form is added and mixed for another 15 minutes. 99 % w/w of the above mixture and up to 1 % w/w of mixture of Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing.

Because of moisture release tendency of the Banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added.

This composition is a result of combining 60% w/w Banana pulp, 10% w/w Biodegradable Polyurethane (Bio PU), 20% w/w Plasticizer, and 10% w/w Oil to create a specialized adhesive composite. The substantial incorporation of 60% w/w EVA contributes mechanical stability and durability to the blend. EVA's synthetic nature ensures resilience and longevity, enhancing the overall adhesive properties. The introduction of 10% w/w Bio PU adds a biodegradable element to the composite. Bio PU, derived from renewable sources, aligns with eco-conscious goals and introduces environmental sustainability to the adhesive. Incorporating 20% w/w plasticizer enhances the adhesive's flexibility and adaptability. Plasticizers contribute to the composite's ability to conform to varying surfaces and conditions. The addition of 10% w/w oil imparts pliability and fluidity to the mixture. The oil content enhances the adhesive's application ease and ensures its spreadability. The culmination of these components results in a composite that harnesses the mechanical strength of EVA, the eco-friendliness of Bio PU, the flexibility of plasticizers, and the application ease provided by oil, yielding an adhesive solution tailored to specific industry needs.

Q. 60% Banana pulp + 30 % polyvinyl acetate + 10 % starch;

Synthetic adhesive like Ethylene Vinyl Acetate, Poly vinyl acetate, Neoprene, plastic resin glue, epoxy glue is mixed with Banana pulp in a_ blender with a blunt spiral structure. Mixing is continued for up to 1 hr with mixing compound elemnets one by one. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying. Starch in liquid form is added and mixed for another 15 minutes. Starch mainly works in this compound as a filler to give fullness and structure to the leather.

99 % w/w of the above mixture and up to 1 % w/w of mixture of Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing.

Because of moisture absorption tendency of starch and moisture release tendency of the Banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added.

R. 55 % Banana pulp + 25 % polyvinyl acetate + 20 % Polymer filler

PVA (polyvinyl acetate) / Ethylene vinyl acetate / Neoprene is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Magnopal IPF is a polymer filler which is added to the above mixture in an amount of 20% w/w of the weight of the composition and mixed for another 30 minutes. This filler imparts fullness and structure to the leather.

Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing and mixed for an hour.

Because of the moisture release tendency of the Banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added.

S. 58% Banana pulp + 21 % polyvinyl acetate + 21 % bio polyurethane as binder ;

PVA (polyvinyl acetate) / Ethylene vinyl acetate / Neoprene is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Bio Polyurethane is added and mixed for another 15 minutes. Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing.

Because of the moisture release tendency of the Banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added.

T. 55 % Banana pulp + 25 % polyvinyl acetate + 20 % Magnopal as filler;

PVA (polyvinyl acetate) / Ethylene vinyl acetate / Neoprene is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Polymer filler Magnopal is added and mixed for another 15 minutes.

Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing.

Because of the moisture release tendency of the Banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added.

U. 60% Banana pulp + 30 % polyvinyl acetate + 10 % starch as filler;

PVA (polyvinyl acetate) / Ethylene vinyl acetate / Neoprene is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Starch in liquid form is added and mixed for another 15 minutes. Starch mainly works in this compound as a filler to give fullness and structure to the leather.

99 % w/w of the above mixture and up to 1 % w/w of mixture of Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing. Because of moisture absorption tendency of starch and moisture release tendency of the Banana pulp, there is a high chance of fungal growth. So, preservatives such as fungicides and bactericide are added.

Softener / plasticizer PEG in liquid form is added to the above mixture and mixed for another 15 minutes. Softener / plasticizer imparts softness to the leather.

Synthetic Colour mixed with double the quantity of suitable Binder is added to the above composition while mixing.

For compositions comprising natural adhesives, processes described below are employed.

First step is preparing natural adhesives. Various natural adhesives are natural rubber, Com starch adhesive, jackfruit glue, Arrowroot Glue etc.

Cornstarch Adhesive - Cornstarch is diluted in hot water in a preferred weight ratio of 1: 6 and mixed properly. Agar agar powder is mixed with hot water in a preferred weight ratio of 1: 5 and gum arabic and gum rosin are also mixed separately with water in a preferred weight ratio of 1: 6.

Further, 60 parts cornstarch solution, 20 parts Agar-agar solution, 10 parts Gum Arabic solution and 5 parts Gum Rosin solution are mixed and heated. Further, from 0.3 to 1.5 parts glycerol, 1 - 2 parts acetic acid, 1 - 1.5 parts Ferrous sulphate are added to above mixture and stirred for 30 min.

Com starch adhesive is ready for incorporation into the compositions of the present invention for preparing Vegan Feather.

Jackfruit Glue

Jackfruit seeds are dried at a temperature of 80°C till they are fully dried. The dried seeds are powdered in a grinder to form dried seed powder. Around 300 - 400 g dried seed powder is mixed with 5 - 8 g of borax and around 2 litres of water. This mixture is subjected to 70-80°C for 10 - 30 minutes after which 1 litre of water is added and mixed and kept aside for 5 - 10 minutes. Jackfruit glue is ready to use.

Arrowroot Glue

Around 40 - 60 g of arrowroot is added to 0.6 - 1 g borax and 180 ml water and mixed properly. The mixture is kept in the hot air oven at a temp of 70- 80°C for around 10 min.

Then 10 -12g NaOH is added to the above mixture and stirred for 15 minutes. Arrowroot Glue is ready to use.

Preparation of compositions comprising natural adhesives a. 60% banana pulp + 20 % Starch + 10% Cork filler + 10% Natural Rubber

Natural rubber is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Specific concentration of the above mixture cork filler and starch are added together for 10 - 30 minutes. The high banana pulp content provides sustainability, potential biodegradability, and a connection to agriculture. Starch enhances the blend's binding and adhesive properties, while cork filler introduces lightweight and insulating qualities. Natural rubber imparts flexibility and durability. This blend can be tailored for applications like eco-friendly packaging materials or even insulating and cushioning materials with agricultural and natural rubber components. b. 50% banana pulp + 10% Jackfruit Glue + 15 % Natural Rubber + 10%

Gum Arabic + 15 % waxes Comprising 50% banana pulp, 10% jackfruit glue, 15% natural rubber, 10% gum arabic, and 15% softener, this composition strikes a balance between natural and synthetic components.

Natural rubber is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Specific concentration of the above jackfruit glue, gum Arabic, waxes are mixed together for 10 - 30 minutes.

Banana pulp adds sustainability and biodegradability, while jackfruit glue and natural rubber provide adhesive and elastic properties. Gum arabic contributes to viscosity, and the softener enhances flexibility. This blend can be utilized for applications ranging from bio-based adhesives to coatings, combining natural and synthetic attributes for versatile use. c. 50% banana pulp + 30% natural rubber + 20% Wheat Straw filler

The mixture of 50% banana pulp, 30% natural rubber, and 20% wheat straw filler creates a composite that combines the sustainability of banana pulp with the durability of natural rubber and the lightweight properties of wheat straw filler.

Natural rubber is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Specific concentration of the above mixture wheat straw filler is mixed together for 10 - 30 minutes. This blend can be employed in applications like eco-friendly construction materials or as a base for biodegradable composites, offering a balanced approach to natural and synthetic components. d. 50% banana pulp + 30% Starch + 20% Guar Gum

Comprising 50% banana pulp, 30% starch, and 20% guar gum, this composition emphasizes natural and plant-based materials.

Guar gum is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Specific concentration of the above mixture starch is mixed together for 10 - 30 minutes.

Banana pulp offers sustainability, while starch and guar gum enhance the blend's binding and thickening properties. This mixture can be used in the creation of environmentally friendly adhesives or biodegradable materials, reflecting a commitment to sustainable alternatives. e. 50% banana pulp + 30% Starch + 20% Veg oil

The composition of 50% banana pulp, 30% starch, and 20% vegetable oil blends natural and plant-based materials to create a versatile mixture.

Starch is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Specific concentration of the above mixture veg oil is mixed together for 10 - 30 minutes. Banana pulp provides sustainability, starch offers binding properties, and vegetable oil introduces lubrication and moisture resistance. This blend can be suitable for applications like biodegradable coatings or as a base for environmentally conscious lubricants. f. 50% banana pulp + 30% Natural Rubber + 20% wheat straw powder

Comprising 50% banana pulp, 30% natural rubber, and 20% wheat straw powder, this composition combines natural and sustainable materials.

Natural rubber is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Specific concentration of the above mixture wheat straw is mixed together for 10 - 30 minutes.

Banana pulp adds eco-friendliness, natural rubber imparts durability, and wheat straw powder introduces lightweight properties. This blend can be employed in applications such as eco-friendly construction materials or as a base for biodegradable composites. g. 50% banana pulp + 30% Gum Arabic solution + 20% Citric acid

The mixture of 50% banana pulp, 30% gum arabic solution, and 20% citric acid emphasizes natural and water-soluble components.

Gum arabic solution is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Specific concentration of the above mixture citric acid is mixed together for 10 - 30 minutes. Banana pulp provides sustainability, gum arabic offers viscosity, and citric acid acts as a natural preservative and pH adjuster. This composition can be used in the formulation of eco-friendly adhesives or as a base for biodegradable solutions, highlighting the use of natural and environmentally conscious materials. h. 50% banana pulp + 30% Talcum powder + 20% natural rubber

Comprising 50% banana pulp, 30% talcum powder, and 20% natural rubber , this composition combines natural materials with mineral fillers.

Natural rubber is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Specific concentration of the above mixture talcum powder is mixed together for 10 - 30 minutes.

Banana pulp brings sustainability, talcum powder offers texture and softness. This blend can be employed in applications like eco-friendly fillers for various products or as a base for biodegradable materials. i. 50% banana pulp + 30% fruit wax + 20% Agar-agar solution

The composition of 50% banana pulp, 30% fruit wax, and 20% agar-agar solution integrates natural and plant-based materials.

Agar-agar solution is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Specific concentration of the above mixture 30% is mixed together for 10 - 30 minutes. Banana pulp provides sustainability, fruit wax introduces texture and protection, and agar-agar solution offers a gelling agent. This blend can be used in applications such as eco-friendly coatings or as a base for biodegradable products, showcasing the versatility of natural components. j. 50% banana pulp + 30% Cork Filler + 20% Natural Rubber

Comprising 50% banana pulp, 30% cork filler, and 20% natural rubber, this composition emphasizes a balance between natural and synthetic materials.

Natural rubber is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Specific concentration of the above mixture cork filler is mixed together for 10 - 30 minutes.

Banana pulp adds sustainability, cork filler introduces lightweight and insulating qualities, and natural rubber imparts flexibility and durability. This blend can be tailored for applications like eco-friendly packaging materials or cushioning materials with a blend of natural and synthetic components. k. 60% banana pulp + 20% Cork Filler + 10% Natural Rubber + 10% wax

The composition of 60% banana pulp, 20% cork filler, 10% natural rubber, and 10% wax offers a blend that combines natural and synthetic materials with a focus on flexibility and texture.

Natural rubber is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying. Specific concentration of the above mixture wax and cork filler are mixed together for 10 - 30 minutes.

Banana pulp provides sustainability, cork filler introduces lightweight properties, natural rubber imparts flexibility and durability, and wax enhances texture and moisture resistance. This blend can be used for applications such as bio-based coatings or as a base for environmentally conscious sealants.

1. 60% banana pulp + 20 % Starch + 10% Cork filler + 10% Guar Gum

Comprising 60% banana pulp, 20% starch, 10% cork filler, and 10% guar gum, this composition balances natural and plant-based materials.

Guar gum is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Specific concentration of the above mixture starch and cork filler are mixed together for 10 - 30 minutes.

Banana pulp provides sustainability, starch and guar gum enhance the blend's binding and thickening properties, and cork filler introduces lightweight and insulating qualities. This mixture can be utilized for applications like eco-friendly adhesives or as a base for biodegradable materials, reflecting a commitment to sustainable alternatives. m. 60% Banana pulp + 30 % natural rubber + 10 % filler like tapioca starch

The mixture of 60% banana pulp, 30% natural rubber, and 10% filler such as starch showcases a blend that combines natural and synthetic components with a focus on sustainability and flexibility.

Natural rubber is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Specific concentration of the above mixture starch filler are mixed together for 10 - 30 minutes. n. 60% Banana pulp + 40 % natural rubber

Comprising 60% banana pulp and 40% natural rubber, this composition places a strong emphasis on natural and sustainable components.

Natural rubber is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Banana pulp offers sustainability, while natural rubber introduces flexibility and durability. This blend can be used for various applications, such as eco-friendly rubber products or materials with a predominantly natural composition. o. 60% Banana pulp + 30 % natural rubber + 10 % citric acid

Natural rubber is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

10 parts of citric acid is mixed together for 10 - 30 minutes. p. 60% Banana pulp + 30 % natural rubber + 10 % jackfruit glue

Natural rubber is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying.

Specific amounts-of the above mixture (mixture of Banana pulp and natural rubber) such as 70 - 90 parts and 10 - 30 parts of jackfruit glue are mixed together for 10 - 30 minutes.

Banana pulp provides sustainability, natural rubber imparts flexibility and durability, and jackfruit glue enhances adhesive qualities. This blend can be used for applications such as bio-based adhesives or as a base for environmentally friendly coatings, showcasing the synergy between natural and synthetic components. q. 60% Banana pulp + 30 % natural rubber + 10 % Arrowroot Glue

Natural rubber is mixed with Banana pulp in a blender with a blunt spiral structure. Mixing is continued for up to 1 hr. This mixture has sufficient adhesiveness to ensure that the composition does not peel off from the backing material after drying. Specific concentration of the above mixture (mixture of Banana pulp and natural rubber) such as 70 - 90 parts and 10 - 30 parts of Arrowroot glue are mixed together for 10 - 30 minutes.

Banana pulp offers sustainability, natural rubber provides flexibility and durability, and arrowroot glue enhances adhesive characteristics. This composition can be utilized for applications like eco-friendly adhesives or as a base for biodegradable materials with a focus on natural and adhesive components.

Example 3 - Preparation of Vegan leather In a first step, backing material is cut into desired dimensions.

In the second step, the backing material is placed on a spraying table. Then 2 coats of any of the compositions are sequentially sprayed on the backing material using a spray gun to produce panels. Panel is backing material coated with compositions / leather mixtures. After first coat, panel is subjected to drying. For various approximate thickness, following coating compositions are preferably applied.

Around 1.7 kg of compound is needed for one 27 by 40 inches fabric for overall 1mm thickness. Backing material of larger size such as 8 X 10 sq. feet or larger larger size can be employed. After spraying, panels are trowelled in which even spreading of coated material is done.

Next step is drying. After trowelling the panels, they are kept in drying racks and are subjected to drying at a specific temperature. Drying temperature is controlled and not allowed to exceed 60°C as it may burn upper soft portion of the coating. Panels are dried for at least 24 hrs., preferably for 48 hrs.

Further, the dried coated panels are subjected sequentially to plating, colour spraying, embossing and lacquering. Drying is needed after each of the steps involving colour spraying, embossing and lacquering.

These steps are described as follows:

Plating

Each panel is subjected to specific temperature and pressure and time. Preferably, pressure of 250 MPa or Bar at 80°C for 1.5 sec. at a second in a hydraulic press machine. Plating softens the upper surface and increases the bonding between fabric /backing material and the layers of coatings.

Further, leather is subjected through various finishing processes.

Finishing

Finishing of leather includes a series of steps to give buyers variety in the colours, embossing, shiny or matt finishes etc. and include spray painting, surface treatment and adding chemicals to stop colour leakage and water proofing etc...

Finishing materials are up to 10 % w/w, preferably up to 5 % w/w of the leather, more preferably from 2% w/w to 4% w/w of the all coating and contains colours, binders, lacquers and water resistant / water repellent coatings. Eacquers include polyurethane lacquers, dyes lacquers, resin based lacquers, different types of Nitrocellulose lacquers, Acrylic Lacquers, and also, water based silicone emulsions etc...

There are a variety of colours which can be employed in the compositions. Some of them are dyes, pigments & natural colours (made from organic compounds like coal tars, some petrochemicals i.e. benzene, toluene, xylene, oil & inorganic compounds like oxidation of metals i.e. titanium, iron etc). Some of the colours are mixed with binders. There is a huge variety in binders. Most commonly, acrylic binders, polyurethane binders, Resin binders etc. are employed.

There is an alternative option of using 100 % w/w bio based binders. Here the binder is made from Natural Rubber and Starch in ratios such as (1:3) or (1:4) or (1:5) or (1:6).

Embossing includes NDM embossed, PDM embossed, YDM embossed, Croco embossed, Printing, Foiling and other types.

Colour Spraying / Spray coating

First coat of colour- After plating the next step is colour coating. Here the Synthetic pigments that are made by some organic and inorganic compounds are used for coating. The pigments used in colour coating are absolutely sustainable and eco friendly. The pigments are mixed with a binder in a ratio from 1:5 to 1:15, preferably in 1:10 ratio.

Surface treatment

After one coat of spray, the panels are kept for drying for 24 hours for fixation of colour.

Next step is surface treatment and includes milling and embossing.

Milling

After colour coating and drying, the panels are subjected to a Milling process to increase the softness. It is a drum operation where the panels are revolved in the drum. Due to this operation the upper surface of the material gets creasing effects like leather finishes.

Embossing It is important to give vegan leather a look of leather. To emboss the upper surface there are many types of plates in the leather industry. Embossing imparts a raised pattern and enhances the look of the leather. There are many plates available in the leather industry. A suitable plate is selected and embossing is done at specific temperature and pressure.

After Embossing, the spray coating step is usually repeated if colours fade during embossing.

The pigments are mixed with a suitable binder in specific ratio from 1:5 to 1:15 preferably, 1:10 and sprayed on the panel. After colour coating, panels are dried for 24 hrs, and then if desired, a second coating is done followed by drying.

Before lacquering the panel, it is mandatory to ensure the colour of the upper surface has dried properly. So, a minimum 24 hours of drying time is needed.

Lacquering.

.Lacquering is done to give desired finish to the prepared leather.

EC, a specific nitrocellulose based lacquer is diluted using water. Additionally, a feeler that modifies touch and feel of a leather such as plant based or silicon based coating emulsion having properties like silicon coating is added to impart smooth touch.

49 % w/w EC lacquer is diluted with 49 % w/w with water and 2 % w/w plant based or silicon based coating emulsion similar properties like silicon coating is mixed in it to provide lacquer suspension. Lacquer suspension is applied as top coat on the prepared leather.

Drying is essential after colour spraying, before and after lacquering. When colour spraying is done multiple times, drying between each spray is essential. Minimum 24 hrs. drying time is used after each colour spraying and before and after Lacquering. During finishing, colours / pigments, binders, preservatives, lacquers, chemicals to prevent colour leakage and water repellents together not more than 5 % w/w are added.

The Vegan leather prepared in accordance with the present invention comprises 1 - 15 % w/w of backing material, colours / pigments, binders, lacquers, chemicals to prevent colour leakage and water repellents and 85 - 99 % w/w of coating composition containing Banana pulp and one or more of additives such as adhesives, binders, fillers, softeners / plasticizers. Additionally, from 0.001 to 0.1 % w/w preservatives are present when required.

Properties of VeganLeather

Vegan leather of the present invention is different from other vegan leathers because it can be made in fully recyclable form when natural / organic backing material is used such as cotton fabric and is therefore 100% w/w bio based. Backing material is It passes all the tests (physical and chemical). There are some physical properties of Vegan Leather produced according to the present invention as follows:

Physical Properties

By using and selecting suitable compositions and suitable backing materials, various vegan leathers of desired properties can be prepared. For example, by choosing tougher backing material, tearing strength can be enhanced. By choosing softer material and adding softeners, tensile strength can be enhanced.

Thickness- The thickness of animal leather is between 1.2mm to 1.8mm. But the thickness of the present Vegan leather can vary between a large range i.e. from 0.7mm to 1.4mm.

Tensile Strength- The tensile strength of leather is 8 to 40 N/mm 2 whereas the tensile of the present Vegan leather is 10- 20 N/ mm 2 . Tearing Strength - The tearing strength of animal leather is 82.9 N/mm. Various Vegan leathers prepared in accordance with the present invention exhibit tearing strength range from 25 - 105 N/mm. Within this range, tensile strength depends on the nature of backing material. For non-woven backing materials made of cotton, polyester and others, tearing strength is 50-105 N/mm and for soft backing material such as woven materials made of cotton, polyester and recycled material, the tearing strength is 30-50N /mm based on the process selected.

Flexing and Elongation - 25 - 35%

Abrasion - The present Vegan leather has water resistance. In dry condition the Vegan leather does not find any coating removal up to 500 revolutions (standard abrasion testing parameter). Waterproofing can further enhance resistance to abrasion.

Colour Fastness of Precipitation- The present Vegan leather passes the test of colour fastness of precipitation which means colour does not fadr during any conditions (wet or dry).

Moisture content- The present Vegan leather material has moisture content up to 3 % w/w and therefore there are no chances of peeling or the coating removal like other vegan leathers. Additionally hydrophilic bacteria cannot affect the panel.

Water Vapour Permeability (WVP)- The present Vegan leather material has low water vapour permeability of up to 0.5 mg/cm 2 /h, preferably up to 0.2 mg/cm 2 /h.

Water Vapour Absorption (WVA)- The present Vegan leather material has water vapour absorption of up to 2 mg/cm 2 .

Chemical Properties

Usually during manufacturing of leather, many toxic / hazardous substances are added especially in processes like tanning and dyeing etc. Some of them are carcinogenic also. Leather produced may contain some traces of hazardous / toxic substances and therefore should be tested for such substances. Commonly such substances include metals like lead, chromium and cadmium. Various hazardous / toxic amines can be employed. Various toxic phthalates can be found in traces.

The present Vegan leather has passed all the chemical tests conducted for absence of hazardous / toxic substances and no such compounds are found in the Vegan Leather produced in accordance with the present invention. Hence Vegan Leather of the present invention is Phthalate free, lead free, chrome free, cadmium free. These are toxic heavy metals found in animal leather due to the tanning process. The Vegan leather is also free of various banned amines, organotin compounds, Polycyclic Aromatic Hydrocarbons (PAHs), Alkylphenols and Alkylphenol Ethoxylates, Short Chain Chlorinated Paraffins, pentachloro phenol.

The pH of the present Vegan leather is 7.5 + 0.2 i.e. almost equal to neutral pH.

Fungal and Bacterial Resistance

Preservatives have been sprayed or added in the process of making. So, there is no chance of bacterial or fungal growth or bacterial existence in the present Vegan leather material.

Composition Specifications

Although there are various finishes, different backings, different outer coverings, different dyes, different machinery operations possible for the present vegan leather. The core process of banana based leather material is consistent.

Backing options

A suitable backing material is selected from recycled plastic bottles, polyester, rayon, nylon, velvet, cotton fabric from a locally grown cotton, vegan fabrics made from banana, bamboo, jute, linen etc..

Overall material composition split The thickness of the backing material in the overall panel is up to 40 % w/w, preferably up to 30 % w/w, more preferably from 5 - 30 % w/w and most preferably from 10 - 30 % w/w and the rest of the coated material is from 60 - 95 % w/w.

In terms of weight, backing material is up to 20 % w/w, preferably up to 10 % w/w and more preferably up to 5 % w/w. Most preferably, coating composition make from 85 - 99 % w/w of the Vegan Leather; and colours / pigments, binders, preservatives, lacquers, chemicals to prevent colour leakage and water repellents together up to 5 % w/w, preferably, from 0.5 - 5 % w/w of final finished leather produced . Vegan leather prepared using compositions of the present invention has employed various natural and synthetic compounds to make the material most effective, usable and suitable for manufacturing various products.

Coating compositions /Leather mixtures

Coating compositions / leather mixtures contain Banana pulp having banana fibres and natural additives like rubber, gums, saps and additional small quantities of substances like PVA, resins, polyurethane, waxes, fillers, starch powder (like Tapioca, corn, potato, rice etc), cork, PEG, Glycerol, IPA, PVC etc is used. It is important to make the leather fungus free, so trace amounts of antifungals, bactericides are used in the manufacturing process.

Finishing compositions

There are various finishes available i.e. in the upper coatings 2-4% w/w different Binders like Protein binder, acrylic binder, PU binder, thermoplastic Binder, non- thermo plastic binders, Butadiene Binder etc; different types of lacquers like Nitrocellulose lacquer, PU lacquer, Acrylic Lacquer; water based silicone emulsion are used. There are various options in the surface treatment and suitable machines are employed during various process steps eg. Milling, Molisa, Hydraulic pressing, Roller coating, splitting, spraying, trowelling etc.

The images of various Vegan leather produced using coating compositions are provided under figures.

Advantageously, the plant-based method of the present invention has at least the following benefits on the environment and livestock.

This plant based leather has wide spread uses across fashion (bags, shoes, belts, wallets), furniture (sofas), and automotive (seats) being the major areas. It is an alternative to a more polluting alternative and also doesn’t harm any animals.

The benefits of this plant-based method are significant CO2 emission savings, the number of livestock saved and the weight in crop waste that was upcycled. Other advantages include waste- water pollution avoided, and resource reduction. Apart from these environmental impacts, measuring additional income for farmers becomes an added advantage of this manufacturing process.

In the environment, carbon emission reduction - Leather is very emission heavy and requires a lot of energy for tanning. Chromium, H2S and other hazardous, carcinogenic animal leather chemicals will be reduced as these are not used in the present invention.

Further, waste reduction is achieved including crop waste from banana stems. Air pollution reduction is achieved by this invention, for example, crop waste that is used is typically burned or degrades on fields.

The present invention also helps in water resource management. The plant-based leather produced in the present invention uses 90% w/w less water than animal leather. Further, the present inventive method is also impactful to avoid animal cruelty. The leather industry is responsible for cruelty to animals (cows, crocodiles, snakes, sheep, goat, buffalo) many of them killed only for their skin, whereas this method completely avoids this.

For farmers also, there is an additional income from sale of banana stem waste in their fields. Also, they have less banana stem waste to deal with and do not need to burn the crop waste, resulting in less pollution.

For the customers, they can get natural, sustainable, vegan, environmentally friendly and cruelty free products.

While certain embodiments have been described, these embodiments have been presented by way of example only, and are not intended to limit the scope of the present disclosure. Indeed, the novel methods, devices, and systems described herein may be embodied in a variety of other forms. Furthermore, various omissions, substitutions, and changes in the form of the methods, devices, and systems described herein may be made without departing from the spirit of the present disclosure.

It is easily perceived that the research could indeed produce material akin to leather.