Title:
PHOTOELECTRIC CONVERSION ELEMENT AND PHOTOELECTROCHEMICAL CELL
Document Type and Number:
WIPO Patent Application WO/2011/108611
Kind Code:
A1
Abstract:
Disclosed is a photoelectric conversion element having high conversion efficiency and furthermore having excellent durability. Further disclosed is a photoelectrochemical cell. The photoelectric conversion element, which comprises a layered structure containing a counter electrode, a charge-transfer body, and a photosensitive body—which has a semiconductor microparticle layer to which a pigment is adsorbed—on a conductive support body, is characterized by the aforementioned pigment having the structure represented by the belowmentioned general formula (1), and by the aforementioned charge-transfer body having an electrolyte composition containing a heterocyclic quaternary salt compound. (In the general formula (1), A1 represents a five- to seven-membered nitrogen-containing heterocycle formed from bonding with a benzene ring. L1 represents an electron-transferring linking group containing a particular heterocycle of a thiophene ring or the like. R1 and R3 each independently represent a hydrogen atom or a substituent group. R2 represents a hydrogen atom or a substituent group. B1 represents a methylene group substituted with an electron-withdrawing group or a heterocyclic acidic nucleus, B1 has at least one acidic group, and n1 represents an integer from 1 to 12.)
Inventors:
SUSUKI TATSUYA (JP)
KOBAYASHI KATSUMI (JP)
KIMURA KEIZO (JP)
KOBAYASHI KATSUMI (JP)
KIMURA KEIZO (JP)
Application Number:
PCT/JP2011/054811
Publication Date:
September 09, 2011
Filing Date:
March 02, 2011
Export Citation:
Assignee:
FUJIFILM CORP (JP)
SUSUKI TATSUYA (JP)
KOBAYASHI KATSUMI (JP)
KIMURA KEIZO (JP)
SUSUKI TATSUYA (JP)
KOBAYASHI KATSUMI (JP)
KIMURA KEIZO (JP)
International Classes:
H01M14/00; C07D233/54; C07D233/56; C07D233/60; C07D409/04; C07D409/14; C07D417/14; C07D495/04; C07D517/04; C09B23/00; H01L31/04
Foreign References:
| JP2010235908A | 2010-10-21 | |||
| JP2011071071A | 2011-04-07 | |||
| JP2001256828A | 2001-09-21 |
Other References:
MASANORI MIYASHITA ET AL.: "Interfacial Electron-Transfer Kinetics in Metal-Free Organic Dye-Sensitized Solar Cells: Combined Effects of Molecular Structure of Dyes and Electrolytes", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 130, 12 September 2008 (2008-09-12), pages 17874 - 17881
ZHONG-SHENG ET AL.: "Exploitation of Ionic Liquid Electrolyte for Dye-Sensitized Solar Cells by Molecular Modification of Organic-Dye Sensitizers", CHEMISTRY OF MATERIALS, vol. 21, 29 May 2009 (2009-05-29), pages 2810 - 2816
HAINING TIAN ET AL.: "Effect of different electron donating groups on the performance of dye-sensitized solar cells", DYES AND PIGMENTS, vol. 84, no. ISS.1, 4 June 2009 (2009-06-04), pages 62 - 68
ZHONG-SHENG ET AL.: "Exploitation of Ionic Liquid Electrolyte for Dye-Sensitized Solar Cells by Molecular Modification of Organic-Dye Sensitizers", CHEMISTRY OF MATERIALS, vol. 21, 29 May 2009 (2009-05-29), pages 2810 - 2816
HAINING TIAN ET AL.: "Effect of different electron donating groups on the performance of dye-sensitized solar cells", DYES AND PIGMENTS, vol. 84, no. ISS.1, 4 June 2009 (2009-06-04), pages 62 - 68
Attorney, Agent or Firm:
IIDA, Toshizo et al. (JP)
Toshizo Iida (JP)
Toshizo Iida (JP)
Download PDF:
Claims: