Title:
METHOD FOR PREPARING BRIGHT HIGH-CONDUCTIVITY GRAPHENE/COPPER COMPOSITE MATERIAL
Document Type and Number:
WIPO Patent Application WO/2022/253114
Kind Code:
A1
Abstract:
The present invention belongs to the technical field of signal transmission, and particularly relates to a method for preparing a bright high-conductivity graphene/copper composite material. In view of the technical problem of bright high-conductivity graphene/copper composite materials being difficult to prepare, provided are a green and environmentally friendly cost-saving graphene/copper deposition solution with a rational ratio and a controllable plating thickness, and an electrodeposition method for preparing a bright high-conductivity graphene/copper composite material having high bonding strength to a substrate and having a smooth surface. First, a graphene/copper deposition solution A containing gelatin and sodium lauryl sulfate as additives is prepared; and then, a pure copper deposition solution B containing polyacrylamide and thiourea as additives is prepared. Deposition is performed by means of alternately depositing the deposition solutions, so as to obtain a bright high-conductivity graphene/copper composite material. The composite material prepared in the present invention has relatively high conductivity while having a smooth and bright surface; in addition, the plating layer has a uniform thickness, the bonding strength to a substrate is high, and the composite material is less prone to being peeled off and detaching.
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Inventors:
WEI KUNXIA (CN)
WANG SHAOPENG (CN)
WEI WEI (CN)
CHU FUQIANG (CN)
DU QINGBO (CN)
WANG SHAOPENG (CN)
WEI WEI (CN)
CHU FUQIANG (CN)
DU QINGBO (CN)
Application Number:
PCT/CN2022/095458
Publication Date:
December 08, 2022
Filing Date:
May 27, 2022
Export Citation:
Assignee:
UNIV CHANGZHOU (CN)
International Classes:
C25D3/38; C25D5/10; C25D7/06; C25D15/00
Foreign References:
| CN113293417A | 2021-08-24 | |||
| CN112064077A | 2020-12-11 | |||
| US20200295427A1 | 2020-09-17 |
Other References:
JIA FEI LONG; WEI KUN XIA; WEI WEI; CHU FU QIANG; DU QING BO; ALEXANDROV IGOR V.; HU JING: "Enhanced Thermal Conductivity and Tensile Strength of Copper Matrix Composite with Few-Layer Graphene Nanoplates", JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE., ASM INTERNATIONAL, MATERIALS PARK, OH., US, vol. 30, no. 10, 28 May 2021 (2021-05-28), US , pages 7682 - 7689, XP037576206, ISSN: 1059-9495, DOI: 10.1007/s11665-021-05902-1
CHENG JUN, DING LIFENG; ZHAO JUNLIANG; WANG TONG; WANG RUONAN; CHEN CHONGYAN; NIU YULAN: "Roles of some additives in continuous electrolytic refining of cathode copper", DIAN DU YU TU SHI = ELECTROPLATING & FINISHING, GUANGDONG QINGGONG DIANDU XUEHUI, CN, vol. 39, no. 7, 15 April 2020 (2020-04-15), CN , pages 383 - 389, XP093010130, ISSN: 1004-227X, DOI: 10.19289/j.1004-227x.2020.07.002
YU O, KURAPOVA, KONAKOV V G, GRASHCHENKO A S, NOVIK N N, GOLUBEV S N, OVID 'KO I A: "71 Nanotwinned copper-graphene composites with high hardness", REVIEWS ON ADVANCED MATERIALS SCIENCE, ADVANCED STUDY CENTER CO., ST. PETERSBURG, RU, vol. 48, no. 1, 1 January 2017 (2017-01-01), RU , pages 71 - 77, XP093010131, ISSN: 1606-5131
"Annual Report on the Development of China's New Materials Industry (2017)", 30 August 2018, METALLURGICAL INDUSTRY PRESS, CN, ISBN: 978-7-5024-7815-5, article NATIONAL EXPERT ADVISORY COMMITTEE ON NEW MATERIALS INDUSTRY DEVELOPMENT: "Passage; Annual Report on the Development of China's New Materials Industry (2017)", pages: 109 - 110, XP009541466
CHENG JUN, DING LIFENG; ZHAO JUNLIANG; WANG TONG; WANG RUONAN; CHEN CHONGYAN; NIU YULAN: "Roles of some additives in continuous electrolytic refining of cathode copper", DIAN DU YU TU SHI = ELECTROPLATING & FINISHING, GUANGDONG QINGGONG DIANDU XUEHUI, CN, vol. 39, no. 7, 15 April 2020 (2020-04-15), CN , pages 383 - 389, XP093010130, ISSN: 1004-227X, DOI: 10.19289/j.1004-227x.2020.07.002
YU O, KURAPOVA, KONAKOV V G, GRASHCHENKO A S, NOVIK N N, GOLUBEV S N, OVID 'KO I A: "71 Nanotwinned copper-graphene composites with high hardness", REVIEWS ON ADVANCED MATERIALS SCIENCE, ADVANCED STUDY CENTER CO., ST. PETERSBURG, RU, vol. 48, no. 1, 1 January 2017 (2017-01-01), RU , pages 71 - 77, XP093010131, ISSN: 1606-5131
"Annual Report on the Development of China's New Materials Industry (2017)", 30 August 2018, METALLURGICAL INDUSTRY PRESS, CN, ISBN: 978-7-5024-7815-5, article NATIONAL EXPERT ADVISORY COMMITTEE ON NEW MATERIALS INDUSTRY DEVELOPMENT: "Passage; Annual Report on the Development of China's New Materials Industry (2017)", pages: 109 - 110, XP009541466
Attorney, Agent or Firm:
CHANGZHOU INNOVATION PATENT AGENCY (CN)
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