Title:
METAL-ORGANIC FRAMEWORK DISPERSION PRODUCTION METHOD, METAL-ORGANIC FRAMEWORK DISPERSION, AND METAL-ORGANIC FRAMEWORK COMPOSITION INCLUDING METAL-ORGANIC FRAMEWORK DISPERSION
Document Type and Number:
WIPO Patent Application WO/2024/048308
Kind Code:
A1
Abstract:
[Problem] To provide a method for using a mechanical pulverization technique to produce a dispersion comprising a nm-size metal-organic framework which has good dispersion stability while maintaining a crystal structure. [Solution] A metal-organic framework dispersion production method comprising: a step (1) for mixing a component (a), which is a solid powder of a metal-organic framework that contains metal ions and organic ligands coordinated to the metal ions, said metal ions being at least one type selected from the group consisting of Zr ions, Al ions, and Zn ions, a component (b), which is a dispersant and which is an aliphatic amine compound that is a primary amine, a secondary amine, or a tertiary amine having one amino group in a molecule thereof, and which is soluble in a dispersion medium (c1), and a component (c1), which is said dispersion medium; and a step (2) for using the obtained mixture to produce a dispersion via a mechanical pulverization technique (wherein in the mechanical pulverization technique, the crystal structure of the metal-organic framework (a) does not change, and the crystal structure of the solid powder is maintained).
Inventors:
WAKITA KENGO (JP)
Application Number:
PCT/JP2023/029742
Publication Date:
March 07, 2024
Filing Date:
August 17, 2023
Export Citation:
Assignee:
NISSAN CHEMICAL CORP (JP)
International Classes:
B01J13/00; C09K23/16
Foreign References:
| CN109248571A | 2019-01-22 | |||
| JP2019056055A | 2019-04-11 | |||
| CN111346525A | 2020-06-30 | |||
| JP2021527074A | 2021-10-11 |
Other References:
JIAO CHENGLI, SONG XIANGJU, ZHANG XIAOQIAN, SUN LIXIAN, JIANG HEQING: "MOF-Mediated Interfacial Polymerization to Fabricate Polyamide Membranes with a Homogeneous Nanoscale Striped Turing Structure for CO 2 /CH 4 Separation", APPLIED MATERIALS & INTERFACES, AMERICAN CHEMICAL SOCIETY, US, vol. 13, no. 15, 21 April 2021 (2021-04-21), US , pages 18380 - 18388, XP093143852, ISSN: 1944-8244, DOI: 10.1021/acsami.1c03737
JIANG DONGMEI, BURROWS ANDREW D., XIONG YULI, EDLER KAREN J.: "Facile synthesis of crack-free metal–organic framework films on alumina by a dip-coating route in the presence of polyethylenimine", JOURNAL OF MATERIALS CHEMISTRY A, ROYAL SOCIETY OF CHEMISTRY, GB, vol. 1, no. 18, 5 April 2013 (2013-04-05), GB , pages 5497, XP093143854, ISSN: 2050-7488, DOI: 10.1039/c3ta10766c
YASSARI MEHRASA; SHAKERI ALIREZA; SALEHI HASAN: "ZIF-67 templated thin-film composite forward osmosis membrane: Importance of incorporation method on morphology and performance", CHEMICAL ENGINEERING RESEARCH AND DESIGN, ELSEVIER, AMSTERDAM, NL, vol. 180, 7 March 2022 (2022-03-07), AMSTERDAM, NL, pages 369 - 378, XP087055987, ISSN: 0263-8762, DOI: 10.1016/j.cherd.2022.03.005
XU XIAOQING, WU PENG, LI CHANGYONG, ZHAO KEYONG, WANG CHIRAN, DENG RENPAN, ZHANG JINLI: "Reversible Removal of SO 2 with Amine-Functionalized ZIF8 Dispersed in n -Heptanol", ENERGY & FUELS, AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC, US., vol. 35, no. 6, 18 March 2021 (2021-03-18), WASHINGTON, DC, US. , pages 5110 - 5121, XP093143859, ISSN: 0887-0624, DOI: 10.1021/acs.energyfuels.0c04271
JIANG DONGMEI, BURROWS ANDREW D., XIONG YULI, EDLER KAREN J.: "Facile synthesis of crack-free metal–organic framework films on alumina by a dip-coating route in the presence of polyethylenimine", JOURNAL OF MATERIALS CHEMISTRY A, ROYAL SOCIETY OF CHEMISTRY, GB, vol. 1, no. 18, 5 April 2013 (2013-04-05), GB , pages 5497, XP093143854, ISSN: 2050-7488, DOI: 10.1039/c3ta10766c
YASSARI MEHRASA; SHAKERI ALIREZA; SALEHI HASAN: "ZIF-67 templated thin-film composite forward osmosis membrane: Importance of incorporation method on morphology and performance", CHEMICAL ENGINEERING RESEARCH AND DESIGN, ELSEVIER, AMSTERDAM, NL, vol. 180, 7 March 2022 (2022-03-07), AMSTERDAM, NL, pages 369 - 378, XP087055987, ISSN: 0263-8762, DOI: 10.1016/j.cherd.2022.03.005
XU XIAOQING, WU PENG, LI CHANGYONG, ZHAO KEYONG, WANG CHIRAN, DENG RENPAN, ZHANG JINLI: "Reversible Removal of SO 2 with Amine-Functionalized ZIF8 Dispersed in n -Heptanol", ENERGY & FUELS, AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC, US., vol. 35, no. 6, 18 March 2021 (2021-03-18), WASHINGTON, DC, US. , pages 5110 - 5121, XP093143859, ISSN: 0887-0624, DOI: 10.1021/acs.energyfuels.0c04271
Attorney, Agent or Firm:
HANABUSA PATENT & TRADEMARK OFFICE (JP)
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