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Title:
逆ミセル抽出系において逆ミセルサイズを制御する方法
Document Type and Number:
Japanese Patent JP5382563
Kind Code:
B2
Abstract:

To provide a method for controlling a reversed micelle size upon producing reversed micelle in an extraction medium phase of the two liquid phase system consisting of water and an extraction medium without adding a large amount of electrolytes.

The method for controlling the reversed micelle size in the extraction medium comprises adding an electrically neutral ligand (molecular ligand) in the two liquid phase system (reversed micelle extraction system) to extract a metal ion or polymer in an aqueous solution into a medium containing the reversed micelle. The control of the reversed micelle size can be performed by only changing the concentration of the molecular ligand to be added when the molecular ligand having the effect to reduce the reversed micelle inner core aqueous phase is utilized. The method is capable of reducing the reversed micelle size while the large extraction ability to the metal is retained. Further, the deacidification or the like are not required for discharging the aqueous phase because nothing is added to the aqueous phase. Also, the extraction medium phase can be utilized repeatedly because the surfactant and molecular ligand are scarcely eluted into the aqueous phase.

COPYRIGHT: (C)2008,JPO&INPIT


Inventors:
Hirochika Naganawa
Kojiro Shimojo
Application Number:
JP2006164769A
Publication Date:
January 08, 2014
Filing Date:
June 14, 2006
Export Citation:
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Assignee:
Japan Atomic Energy Agency
International Classes:
B01D11/02; C01F17/00
Domestic Patent References:
JP2003275751A
JP2004149738A
JP2005290481A
JP2006036866A
Other References:
長縄弘親ら,"Cooperative effect of carbamoylmethylene phosphine oxide on the extraction of lanthanides(III) to water-in-oil microemulsion from concentrated nitric acid medium",Physical Chemistry Chemical Physics,2000年,2巻,3247-3253
Attorney, Agent or Firm:
Shinjiro Ono
Yasushi Kobayashi
Akio Chiba
Hiroyuki Tomita
Shurin Sakurai



 
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