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Title:
PROCESS FOR MAKING A GRAFTED POLYOLEFIN
Document Type and Number:
WIPO Patent Application WO/2024/020827
Kind Code:
A1
Abstract:
A process for manufacturing a grafted polyolefin having improved yellowness properties, the process including reacting an admixture of: (i) at least one polyolefin; (ii) at least one monomer; wherein the at least one monomer is selected from one or more acid compounds having the following general chemical Formula (I) or Formula (II); wherein in Formula (I) and Formula (II) either R1 or R2 is H, with the proviso that both R1 and R2 is not H; wherein at least one of R1 and R2 is an alkyl or an alkenyl with a carbon number of from 1 to 20; and wherein R1, R2, or both R1 and R2 may further include an ester, a heteroatom, an aromatic, or a halogen; and (iii) at least one free radical initiator to form a grafted polyolefin; wherein the grafted polyolefin has a yellowness index, YIE313, of < 30.

Inventors:
HE CHAO (CN)
ZHANG KAINAN (CN)
SUN YABIN (CN)
SENGUPTA SAURAV (US)
COGEN JEFFREY (US)
YANG XIUHAN (CN)
WANG GUOWEI (CN)
Application Number:
PCT/CN2022/108127
Publication Date:
February 01, 2024
Filing Date:
July 27, 2022
Export Citation:
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Assignee:
DOW GLOBAL TECHNOLOGIES LLC (US)
DOW SILICONES CORP (US)
HE CHAO (CN)
ZHANG KAINAN (CN)
SUN YABIN (CN)
SENGUPTA SAURAV (US)
COGEN JEFFREY M (US)
YANG XIUHAN (CN)
WANG GUOWEI (CN)
International Classes:
C08F255/02; C08F255/00
Foreign References:
US20210363281A12021-11-25
CN107286854A2017-10-24
EP0517128A21992-12-09
US20090076212A12009-03-19
US5728776A1998-03-17
US6380320B12002-04-30
Other References:
KIM JUNG-SOO, BAE JONG-WOO, LEE JIN-HYOK, OH SANG-TAEK, KIM GU-NI, LEE YOUNG-HEE, KIM HAN-DO: "Melt Grafting of Citraconic Acid onto an Ethylene-Propylene-Diene Terpolymer (EPDM) -Effect of Reaction Conditions and Initiator Type on the Melt Grafting of Citraconic Acid onto EPDM-", ELASTOMERS AND COMPOSITES, vol. 48, no. 1, 31 March 2013 (2013-03-31), pages 39 - 45, XP093133051, ISSN: 2092-9676, DOI: 10.7473/EC.2013.48.1.39
Attorney, Agent or Firm:
WU, FENG & ZHANG (CN)
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