Title:
PROCESS FOR MAKING A GRAFTED POLYOLEFIN
Document Type and Number:
WIPO Patent Application WO/2024/020827
Kind Code:
A1
Abstract:
A process for manufacturing a grafted polyolefin having improved yellowness properties, the process including reacting an admixture of: (i) at least one polyolefin; (ii) at least one monomer; wherein the at least one monomer is selected from one or more acid compounds having the following general chemical Formula (I) or Formula (II); wherein in Formula (I) and Formula (II) either R1 or R2 is H, with the proviso that both R1 and R2 is not H; wherein at least one of R1 and R2 is an alkyl or an alkenyl with a carbon number of from 1 to 20; and wherein R1, R2, or both R1 and R2 may further include an ester, a heteroatom, an aromatic, or a halogen; and (iii) at least one free radical initiator to form a grafted polyolefin; wherein the grafted polyolefin has a yellowness index, YIE313, of < 30.
Inventors:
HE CHAO (CN)
ZHANG KAINAN (CN)
SUN YABIN (CN)
SENGUPTA SAURAV (US)
COGEN JEFFREY (US)
YANG XIUHAN (CN)
WANG GUOWEI (CN)
ZHANG KAINAN (CN)
SUN YABIN (CN)
SENGUPTA SAURAV (US)
COGEN JEFFREY (US)
YANG XIUHAN (CN)
WANG GUOWEI (CN)
Application Number:
PCT/CN2022/108127
Publication Date:
February 01, 2024
Filing Date:
July 27, 2022
Export Citation:
Assignee:
DOW GLOBAL TECHNOLOGIES LLC (US)
DOW SILICONES CORP (US)
HE CHAO (CN)
ZHANG KAINAN (CN)
SUN YABIN (CN)
SENGUPTA SAURAV (US)
COGEN JEFFREY M (US)
YANG XIUHAN (CN)
WANG GUOWEI (CN)
DOW SILICONES CORP (US)
HE CHAO (CN)
ZHANG KAINAN (CN)
SUN YABIN (CN)
SENGUPTA SAURAV (US)
COGEN JEFFREY M (US)
YANG XIUHAN (CN)
WANG GUOWEI (CN)
International Classes:
C08F255/02; C08F255/00
Foreign References:
US20210363281A1 | 2021-11-25 | |||
CN107286854A | 2017-10-24 | |||
EP0517128A2 | 1992-12-09 | |||
US20090076212A1 | 2009-03-19 | |||
US5728776A | 1998-03-17 | |||
US6380320B1 | 2002-04-30 |
Other References:
KIM JUNG-SOO, BAE JONG-WOO, LEE JIN-HYOK, OH SANG-TAEK, KIM GU-NI, LEE YOUNG-HEE, KIM HAN-DO: "Melt Grafting of Citraconic Acid onto an Ethylene-Propylene-Diene Terpolymer (EPDM) -Effect of Reaction Conditions and Initiator Type on the Melt Grafting of Citraconic Acid onto EPDM-", ELASTOMERS AND COMPOSITES, vol. 48, no. 1, 31 March 2013 (2013-03-31), pages 39 - 45, XP093133051, ISSN: 2092-9676, DOI: 10.7473/EC.2013.48.1.39
Attorney, Agent or Firm:
WU, FENG & ZHANG (CN)
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