Title:
PREPARATION METHOD FOR MAGNETIC COVALENT ORGANIC FRAMEWORK, MTFBD-PPD, PRODUCT AND USE THEREOF
Document Type and Number:
WIPO Patent Application WO/2022/188209
Kind Code:
A1
Abstract:
A preparation method for a magnetic covalent organic framework, mTFBD-PPD, a product and the use thereof, which belong to the technical field of preparation of a toxin adsorbent. The preparation method comprises: dissolving 3,3',5,5'-tetraaldehyde-4,4'-dihydroxybiphenyl and an alkali in water to obtain a solution; dispersing p-phenylenediamine and magnetic nanoparticles in an organic solvent to obtain a dispersion; and mixing the solution with the dispersion, and reacting same to obtain a magnetic covalent organic framework, mTFBD-PPD. The new adsorbent, mTFBD-PPD, which is prepared by combining a covalent organic framework material with magnetic nanoparticles, has the characteristics of a large specific surface area, good thermal stability, a strong selectivity, being capable of rapid separation, being reusable, etc.; and same can effectively improve the adsorption rate during the use thereof in the adsorption of diarrhetic shellfish toxins.
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Inventors:
XIE WANCUI (CN)
YANG XIHONG (CN)
SONG LIN (CN)
CHE HONGXIA (CN)
DONG XIUFANG (CN)
LI HONGYAN (CN)
DONG ZEQUN (CN)
GUO HAO (CN)
YANG XIHONG (CN)
SONG LIN (CN)
CHE HONGXIA (CN)
DONG XIUFANG (CN)
LI HONGYAN (CN)
DONG ZEQUN (CN)
GUO HAO (CN)
Application Number:
PCT/CN2021/083288
Publication Date:
September 15, 2022
Filing Date:
March 26, 2021
Export Citation:
Assignee:
QINGDAO UNIV OF SCIENCE AND TECHNOLOGY (CN)
International Classes:
B01J20/26; C08G12/08; B01J20/28; B01J20/30; C02F1/28; C08K3/22; C08K9/06
Foreign References:
| CN110157008A | 2019-08-23 | |||
| CN110090624A | 2019-08-06 | |||
| CN110215905A | 2019-09-10 |
Other References:
NIU LIN;WU AIMING;WANG JUNYU;WANG HONGYANG;TANG ZHI;WANG XIA;ZHAO XIAOLI: "Advances in Preparation Methods of Magnetic Covalent Organic Frameworks", RESEARCH OF ENVIRONMENTAL SCIENCES, vol. 33, no. 9, 12 March 2020 (2020-03-12), pages 2118 - 2128, XP055965950, ISSN: 1001-6929, DOI: 10.13198/j.issn.1001-6929.2020.03.04
ZHANG LEI, LIANG RONGRAN, HANG CHENG, WANG HAIYING, SUN LIN, XU LEI, LIU DAIRONG, ZHANG ZHENYI, ZHANG XINGMIN, CHANG FEIFAN, ZHAO : "A facile solution-phase synthetic approach for constructing phenol-based porous organic cages and covalent organic frameworks", GREEN CHEMISTRY, vol. 22, no. 8, 1 January 2020 (2020-01-01), GB , pages 2498 - 2504, XP055965672, ISSN: 1463-9262, DOI: 10.1039/C9GC04033A
SALONEN LAURA M; PINELA SARA R; FERNANDES SORAIA P S; LOUÇANO JOÃO; CARBÓ-ARGIBAY ENRIQUE; SARRIÁ MARISA P; RODRÍGUEZ-ABREU CARLOS: "Adsorption of marine phycotoxin okadaic acid on a covalent organic framework", JOURNAL OF CHROMATOGRAPHY A, vol. 1525, 24 November 2017 (2017-11-24), AMSTERDAM, NL, pages 17 - 22, XP085274445, ISSN: 0021-9673, DOI: 10.1016/j.chroma.2017.10.017
ZHANG LEI, LIANG RONGRAN, HANG CHENG, WANG HAIYING, SUN LIN, XU LEI, LIU DAIRONG, ZHANG ZHENYI, ZHANG XINGMIN, CHANG FEIFAN, ZHAO : "A facile solution-phase synthetic approach for constructing phenol-based porous organic cages and covalent organic frameworks", GREEN CHEMISTRY, vol. 22, no. 8, 1 January 2020 (2020-01-01), GB , pages 2498 - 2504, XP055965672, ISSN: 1463-9262, DOI: 10.1039/C9GC04033A
SALONEN LAURA M; PINELA SARA R; FERNANDES SORAIA P S; LOUÇANO JOÃO; CARBÓ-ARGIBAY ENRIQUE; SARRIÁ MARISA P; RODRÍGUEZ-ABREU CARLOS: "Adsorption of marine phycotoxin okadaic acid on a covalent organic framework", JOURNAL OF CHROMATOGRAPHY A, vol. 1525, 24 November 2017 (2017-11-24), AMSTERDAM, NL, pages 17 - 22, XP085274445, ISSN: 0021-9673, DOI: 10.1016/j.chroma.2017.10.017
Attorney, Agent or Firm:
BEIJING DONGFANG SHENGFAN IP AGENT FIRM GP (CN)
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