Title:
METHOD FOR PRODUCING POLYMER, COMPOSITION FOR RADICAL POLYMERIZATION, AND RADICAL POLYMERIZATION INHIBITOR
Document Type and Number:
WIPO Patent Application WO/2022/191288
Kind Code:
A1
Abstract:
A method for producing a polymer which includes a polymerization step in which controlled radical polymerization of a monomer (Y) is conducted in the presence of an organic compound (A) represented by formula (I) and a radical generator (B), the molar ratio of (B) to (A), B/A, being 0.5-20. According to the production method, a high-molecular-weight polymer having high safety can be synthesized with precise regulation of the molecular arrangement, terminal structure, etc. Furthermore, the production method is lowly toxic, is friendly to the environment, and is inexpensive. [In formula (I), R1 is an alkenyl or aryl group, R2 is a group represented by formula (II) or (III), and R1 and R2 may have been bonded to each other to form a ring.] [In formula (II), R3 is a hydrogen atom, a halogen atom, or an alkyl, aryl, alkenyl, alkoxy, amino, nitro, cyano, acetyl, trifluoromethyl, or hydroxyl group and * indicates a bond.] [In formula (III), R3 has the same meaning as in formula (II) and * indicates a bond.]
Inventors:
TAKAYAMA TAKUMI (JP)
TSUCHIYA HINAKO (JP)
MAEKAWA KAZUHIKO (JP)
TSUCHIYA HINAKO (JP)
MAEKAWA KAZUHIKO (JP)
Application Number:
PCT/JP2022/010635
Publication Date:
September 15, 2022
Filing Date:
March 10, 2022
Export Citation:
Assignee:
KURARAY CO (JP)
International Classes:
C08F18/04; C08F2/38; C08F293/00
Domestic Patent References:
| WO2017170974A1 | 2017-10-05 | |||
| WO2017170974A1 | 2017-10-05 |
Foreign References:
| JP2018536055A | 2018-12-06 | |||
| CN110938183A | 2020-03-31 | |||
| JP2007112937A | 2007-05-10 | |||
| JP2010222285A | 2010-10-07 | |||
| JP2014129503A | 2014-07-10 | |||
| JP2002053728A | 2002-02-19 |
Other References:
CHEN MING, GHIGGINO KENNETH P., MAU ALBERT W. H., RIZZARDO EZIO, SASSE WOLFGANG H. F., THANG SAN H., WILSON GERARD J.: "Synthesis of Functionalized RAFT Agents for Light Harvesting Macromolecules", MACROMOLECULES, AMERICAN CHEMICAL SOCIETY, US, vol. 37, no. 15, 1 July 2004 (2004-07-01), US , pages 5479 - 5481, XP055964940, ISSN: 0024-9297, DOI: 10.1021/ma049037k
"Highly Efficient Cobalt-Mediated Radical Polymerization of Vinyl Acetate", ANGEWANDTE CHEMIE INTERNATIONAL EDITION, vol. 44, 2005, pages 1101 - 1104
"Radical Copolymerizability of Alkyl Cinnamate and Alkyl Atropate", JOURNAL OF INDUSTRIAL CHEMISTRY, vol. 70, no. 11, 1967, pages 1941 - 1944
NATURE CHEMISTRY, vol. 6, 2014, pages 179 - 187
"Polymer Handbook", pages: II/273
"Highly Efficient Cobalt-Mediated Radical Polymerization of Vinyl Acetate", ANGEWANDTE CHEMIE INTERNATIONAL EDITION, vol. 44, 2005, pages 1101 - 1104
"Radical Copolymerizability of Alkyl Cinnamate and Alkyl Atropate", JOURNAL OF INDUSTRIAL CHEMISTRY, vol. 70, no. 11, 1967, pages 1941 - 1944
NATURE CHEMISTRY, vol. 6, 2014, pages 179 - 187
"Polymer Handbook", pages: II/273
Attorney, Agent or Firm:
SETOUCHI INTERNATIONAL PATENT FIRM (JP)
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