Title:
METHOD FOR PREPARING POLYTHIOIMIDATE BASED ON MULTI-COMPONENT POLYMERIZATION OF ALKYNE, SULFONYL AZIDE AND THIOL
Document Type and Number:
WIPO Patent Application WO/2024/011744
Kind Code:
A1
Abstract:
The present application relates to a method for preparing polythioimidate on the basis of multi-component polymerization of alkyne, sulfonyl azide and thiol. The method comprises the following steps: performing a multi-component polymerization reaction on a diyne monomer, a dithiol monomer, sulfonyl azide and alkali in a reaction solvent under the action of a monovalent copper catalyst in a protective atmosphere to obtain polythioimidate. The method is simple to operate, mild in reaction condition and high in atom economy; only nitrogen byproducts are generated; the group tolerance is strong; a plurality of functional groups can be introduced into the monomers; the weight-average molecular weight of polythioimidate ranges from 4000 g/mol to 13000 g/mol; and the polythioimidate has excellent selective adsorption properties on heavy metal nickel ions (Ni2+), and has a unique application value in the aspect of enrichment of heavy metal ions.
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Inventors:
SUN JIANYU (CN)
ZHENG NAN (CN)
ZHANG YUEZONG (CN)
KONG LINGMI (CN)
WANG DAWEI (CN)
HE JUNNAN (CN)
WAN HONGGANG (CN)
ZHAN XUEQI (CN)
ZHENG NAN (CN)
ZHANG YUEZONG (CN)
KONG LINGMI (CN)
WANG DAWEI (CN)
HE JUNNAN (CN)
WAN HONGGANG (CN)
ZHAN XUEQI (CN)
Application Number:
PCT/CN2022/118686
Publication Date:
January 18, 2024
Filing Date:
September 14, 2022
Export Citation:
Assignee:
JIANGSU ZHONGLI GROUP CO LTD (CN)
UNIV DALIAN TECH (CN)
UNIV DALIAN TECH (CN)
International Classes:
C08G75/045; C08G75/30
Foreign References:
| CN114891216A | 2022-08-12 | |||
| CN109161017A | 2019-01-08 | |||
| CN113214477A | 2021-08-06 | |||
| CN113402710A | 2021-09-17 | |||
| CN110483773A | 2019-11-22 |
Other References:
ZHENG, NAN ET AL.: "Multicomponent polymerization toward biodegradable polymers with diverse responsiveness in tumor microenvironments", POLYMER CHEMISTRY, vol. 11, no. 6, 23 December 2019 (2019-12-23), XP093012637, ISSN: 1759-9954, DOI: 10.1039/C9PY01576K
KIM HYUNSEOK, CHOI TAE-LIM: "Preparation of a Library of Poly( N -sulfonylimidates) by Cu-Catalyzed Multicomponent Polymerization", ACS MACRO LETTERS, vol. 3, no. 8, 19 August 2014 (2014-08-19), pages 791 - 794, XP093012663, ISSN: 2161-1653, DOI: 10.1021/mz5003239
HUANG DIE, LIU YONG, QIN ANJUN, TANG BEN ZHONG: "Recent advances in alkyne-based click polymerizations", POLYMER CHEMISTRY, ROYAL SOCIETY OF CHEMISTRY, CAMBRIDGE, vol. 9, no. 21, 1 January 2018 (2018-01-01), Cambridge , pages 2853 - 2867, XP093128698, ISSN: 1759-9954, DOI: 10.1039/C7PY02047C
KIM HYUNSEOK, CHOI TAE-LIM: "Preparation of a Library of Poly( N -sulfonylimidates) by Cu-Catalyzed Multicomponent Polymerization", ACS MACRO LETTERS, vol. 3, no. 8, 19 August 2014 (2014-08-19), pages 791 - 794, XP093012663, ISSN: 2161-1653, DOI: 10.1021/mz5003239
HUANG DIE, LIU YONG, QIN ANJUN, TANG BEN ZHONG: "Recent advances in alkyne-based click polymerizations", POLYMER CHEMISTRY, ROYAL SOCIETY OF CHEMISTRY, CAMBRIDGE, vol. 9, no. 21, 1 January 2018 (2018-01-01), Cambridge , pages 2853 - 2867, XP093128698, ISSN: 1759-9954, DOI: 10.1039/C7PY02047C
Attorney, Agent or Firm:
SUZHOU JINHE INTELLECTUAL PROPERTY AGENCY (SPECIAL GENERAL PARTNERSHIP) (CN)
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