Title:
METAL BRIDGE SITE FUSED RING COMPOUND, AND INTERMEDIATE, PREPARATION METHOD AND USE THEREOF
Document Type and Number:
WIPO Patent Application WO/2016/180297
Kind Code:
A1
Abstract:
The present invention relates to the fields of organic chemistry and metal organic chemistry, disclosed are a metal bridge site fused ring compound, and an intermediate, a preparation method and a use thereof, the metal bridge site fused ring compound has a structure represented by any one of formulae I* to VI* and formulae I'* to VI'*, and the intermediate of the metal bridge site fused ring compound of the present invention has a structure represented by formula I. The chain polyyne compound provided by the present invention contains multiple functional groups, has a controllable structure, and can be used for efficiently synthesizing a metal fused heterocyclic compound. The metal bridge site fused ring compound of the present invention has application prospects in the fields of solar cells, photodynamic therapy, photolysis of water and lithium-air batteries. The main structure of the metal bridge site fused ring compound provided by the present invention has a good planarity, is a large conjugated system, has an aromaticity and good stability, has a good UV-visible-NIR absorption spectrum and better electrochemical performance.
Inventors:
XIA HAIPING (CN)
ZHUO QINGDE (CN)
LIN JIANFENG (CN)
ZHOU XIAOXI (CN)
CHEN ZHIXIN (CN)
SHAO YIFAN (CN)
ZHANG HONG (CN)
HE XUMIN (CN)
ZHUO QINGDE (CN)
LIN JIANFENG (CN)
ZHOU XIAOXI (CN)
CHEN ZHIXIN (CN)
SHAO YIFAN (CN)
ZHANG HONG (CN)
HE XUMIN (CN)
Application Number:
PCT/CN2016/081392
Publication Date:
November 17, 2016
Filing Date:
May 09, 2016
Export Citation:
Assignee:
UNIV XIAMEN (CN)
International Classes:
C07D333/24; C07C29/00; C07C33/04; C07C41/18; C07C41/26; C07C43/178; C07C67/317; C07C69/732; C07C215/24; C07C247/08; C07F7/08; C07F15/00
Other References:
ZHU, CONGQING ET AL.: "Synthesis of the Metal Bridge Fused Ring Aromatic Compound", 17 TH NATIONAL ORGANOMETALLIC CHEMICAL SYMPOSIUM, 31 October 2012 (2012-10-31), pages 20
XIA, HAIPING ET AL.: "A New Aromatic System Formed by ''Carbonic Dragon'' and Transition Metals", 18TH NATIONAL ORGANOMETALLIC CHEMICAL SYMPOSIUM, 31 August 2014 (2014-08-31), pages 4
ZHU, CONGQING ET AL.: "Stabilizing Two Classical Antiaromatic Frameworks: Demonstration of PhotoacoUStic Imaging and the Photothermal Effect in Metalla-aromatics", ANGEW.CHEM.INT.ED., vol. 54, no. 21, 30 March 2015 (2015-03-30), pages 6181 - 6185, XP055328260
ZHU, CONGQING ET AL.: "Planar Mobius Aromatic Pentalenes Incorporating 16 and 18 valence Electron Osmiums", NATURE COMMUNICATIONS, 25 February 2014 (2014-02-25), pages 3265, XP055328265
KULKARNI, B.A.S. ET AL.: "Synthesis of Some Bioactive Acetylenic Alcohols, Components of the Marine Sponge Cribrochalina vasculum", J.ORG.CHEM., vol. 58, no. 22, 31 December 1993 (1993-12-31), pages 5964 - 5966, XP055328267
XIA, HAIPING ET AL.: "A New Aromatic System Formed by ''Carbonic Dragon'' and Transition Metals", 18TH NATIONAL ORGANOMETALLIC CHEMICAL SYMPOSIUM, 31 August 2014 (2014-08-31), pages 4
ZHU, CONGQING ET AL.: "Stabilizing Two Classical Antiaromatic Frameworks: Demonstration of PhotoacoUStic Imaging and the Photothermal Effect in Metalla-aromatics", ANGEW.CHEM.INT.ED., vol. 54, no. 21, 30 March 2015 (2015-03-30), pages 6181 - 6185, XP055328260
ZHU, CONGQING ET AL.: "Planar Mobius Aromatic Pentalenes Incorporating 16 and 18 valence Electron Osmiums", NATURE COMMUNICATIONS, 25 February 2014 (2014-02-25), pages 3265, XP055328265
KULKARNI, B.A.S. ET AL.: "Synthesis of Some Bioactive Acetylenic Alcohols, Components of the Marine Sponge Cribrochalina vasculum", J.ORG.CHEM., vol. 58, no. 22, 31 December 1993 (1993-12-31), pages 5964 - 5966, XP055328267
Attorney, Agent or Firm:
RUNPING & PARTNERS (CN)
北京润平知识产权代理有限公司 (CN)
北京润平知识产权代理有限公司 (CN)
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