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Title:
EMERGENCY RESCUE & AID SUPPORT SYSTEM - ERASS
Document Type and Number:
WIPO Patent Application WO/2024/084490
Kind Code:
A1
Abstract:
The present invention "ERASS" provides an Unmanned Aerial Vehicle (UAV) based lifesaving vests/buoy and/or lifesaving kits dropping system. The UAV lifesaving kits dropping device comprises of a lifesaving kit which provides the connecting link from rescuer to victim. Wherein the connecting mechanism comprises the life buoy which is fixed to the body of the drone. The dropping mechanism enables the delivery of lifesaving equipment's/kits is installed in the critical lifesaving delivery mechanism and comprises a steering motor, guiding ropes and the control mechanism and other equipment's is installed on the system and also other surveillance and other rescue sensors, equipment's can be enables in the same system for an effective rescue operation. In the UAV based life buoy dropping device, the design of utilizing the baffles to block the life buoy is adopted, one or multiple life buoys can be accurately dropped multiple lifesaving kits for multiple times, and one unmanned aerial vehicle can rescue multiple targets during the operation. The core of this invention is to provide the interlinking mechanism between the victims and ground rescue team through a physical connect mechanism.

Inventors:
RAM KISHORE THANDAL MURALIRAJA (IN)
BALAGANESAN G (IN)
SUNDARARAJAN R (IN)
Application Number:
PCT/IN2023/000010
Publication Date:
April 25, 2024
Filing Date:
October 12, 2023
Export Citation:
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Assignee:
RAM KISHORE THANDAL MURALIRAJA (IN)
International Classes:
B64U101/55
Download PDF:
Claims:
Alkenyl groups may have 2 to 30, alternatively 2 to 24, alternatively 2 to 20, alternatively 2 to 12, alternatively 2 to 10, and alternatively 2 to 6 carbon atoms. Possible alkenyl groups are exemplified by, but not limited to, vinyl, allyl, methallyl, propenyl, and hexenyl and cyclohexenyl groups. Alkynyl groups may have 2 to 30, alternatively 2 to 24, alternatively 2 to 20, alternatively 2 to 12, alternatively 2 to 10, and alternatively 2 to 6 carbon atoms. Alkynyl groups may be exemplified by, but not limited to, ethynyl, propynyl, and butynyl groups. Component (a) has multiple units of the formula (I): R’aSiO(4-a)/2 (I) in which each R’ is independently selected from an aliphatic hydrocarbyl, or aliphatic non- halogenated organyl group (that is any aliphatic organic substituent group, regardless of functional type, having one free valence at a carbon atom). Saturated aliphatic hydrocarbyls are exemplified by, but not limited to alkyl groups such as methyl, ethyl, propyl, pentyl, octyl, undecyl, and octadecyl and cycloalkyl groups such as cyclohexyl. Unsaturated aliphatic hydrocarbyls are exemplified by, but not limited to the alkenyl groups and alkynyl groups described above. The aliphatic non-halogenated organyl groups are exemplified by, but not limited to, suitable nitrogen containing groups such as amido groups, imido groups; oxygen containing groups such as polyoxyalkylene groups, carbonyl groups, alkoxy groups and hydroxyl groups. The subscript “a” is 0, 1, 2 or 3, typically in this instance a is mainly 2 but may contain some units where a is 1 or 3. Siloxy units may be described by a shorthand (abbreviated) nomenclature, namely - "M," "D," "T," and "Q", when R’ is as described above, alternatively an alkyl group, typically a methyl group The M unit corresponds to a siloxy unit where a = 3, that is R’3SiO1/2; the D unit corresponds to a siloxy unit where a = 2, namely R’2SiO2/2; the T unit corresponds to a siloxy unit where a = 1, namely R’1SiO3/2; the Q unit corresponds to a siloxy unit where a = 0, namely SiO4/2. The polyorganosiloxane, such as a polydiorganosiloxane of component (a), is substantially linear but may contain a proportion of branching due to the presence of T units (as previously described) within the molecule, hence the average value of subscript a in structure (I) is about 2. Examples of typical R’ groups on component (a) the one or more polyorganosiloxanes containing at least two unsaturated groups, selected from alkenyl groups and alkynyl groups, per molecule, include mainly alkyl groups, especially methyl and ethyl, alternatively methyl groups but may also include aryl groups and/or fluoroalkyl groups such as trifluoropropyl or perfluoroalkyl groups in addition to the required at least two unsaturated groups selected from alkenyl and/or alkynyl groups, typically alkenyl groups The groups may be in pendent position (on a D or T siloxy unit) or may be terminal (on an M siloxy unit). Hence, the polymer chain of component (a) may be selected from polydimethylsiloxanes, alkylmethylpolysiloxanes, alkylarylpolysiloxanes or copolymers thereof (where reference to alkyl means any suitable alkyl group, alternatively an alkyl group having two or more carbons) providing each component (a) polymer comprises at least two alkenyl and or alkynyl groups, typically at least two alkenyl groups. Such polymer chains may have any suitable terminal groups, for example, they may be trialkyl terminated, alkenyldialkyl terminated alkynyldialkyl terminated or may be terminated with any other suitable terminal group combination providing each polymer contains at least two unsaturated groups selected from alkenyl and alkynyl groups per molecule. In one embodiment the terminal groups of such a polymer don’t comprise any silanol terminal groups. Hence component (a) may, for the sake of example, be: a dialkylalkenyl terminated polydimethylsiloxane, e.g., dimethylvinyl terminated polydimethylsiloxane; a dialkylalkenyl terminated dimethylmethylphenylsiloxane, e.g., dimethylvinyl terminated dimethylmethylphenylsiloxane; a trialkyl terminated dimethylmethylvinyl polysiloxane; a dialkylvinyl terminated dimethylmethylvinyl polysiloxane copolymer; a dialkylvinyl terminated methylphenylpolysiloxane, a dialkylalkenyl terminated methylvinylmethylphenylsiloxane; a dialkylalkenyl terminated methylvinyldiphenylsiloxane; a dialkylalkenyl terminated methylvinyl methylphenyl dimethylsiloxane; a trimethyl terminated methylvinyl methylphenylsiloxane; a trimethyl terminated methylvinyl diphenylsiloxane; or a trimethyl terminated methylvinyl methylphenyl dimethylsiloxane. Component a) has a viscosity of from 1000 mPa.s to 100,000 mPa.s at 25oC, alternatively 5000 mPa.s to 75,000 mPa.s at 25oC, 10,000 mPa.s to 60,000 mPa.s at 25oC and is preferably present in an amount of from 25 to 60 wt. % of the composition, alternatively in an amount of from 30 to 60 wt. % of the composition, alternatively in an amount of from 35 to 55 wt. % of the composition. Viscosity may be measured at 25 °C using either a BrookfieldTM rotational viscometer with spindle LV-4 for viscosities over 15,000mPa.s (Spindle LV-4 designed for viscosities in the range between 1,000-2,000,000 mPa.s) at an appropriate rpm and using a BrookfieldTM rotational viscometer with a cone plate arrangement with cone CP-52 for viscosities up to 15, 000mPa.s at 25°C and an appropriate rpm. Component (b) Component (b) functions as a cross-linker and is provided in the form of an organosilicon compound having at least two, alternatively at least three Si-H groups per molecule. Component (b) normally contains three or more silicon-bonded hydrogen atoms so that the hydrogen atoms can react with the unsaturated alkenyl and/or alkynyl groups of component (a) to form a network structure therewith and thereby cure the composition. Some or all of Component (b) may alternatively have two silicon bonded hydrogen atoms per molecule when polymer (a) has greater than two unsaturated groups per molecule. The molecular configuration of the organosilicon compound having at least two, alternatively at least three Si-H groups per molecule (b) is not specifically restricted. It may be a polyorganosiloxane which can have a straight chain, be branched (a straight chain with some branching through the presence of T groups), cyclic or be a silicone resin based. While the molecular weight of component (b) is not specifically restricted, the viscosity is typically from 5 to 50,000 mPa.s at 25ºC using the test methodology as described for component (a). Silicon-bonded organic groups used in component (b) may be exemplified by alkyl groups such as methyl, ethyl, propyl, n-butyl, t-butyl, pentyl, hexyl; aryl groups such as phenyl tolyl, xylyl, or similar aryl groups; 3-chloropropyl, 3,3,3-trifluoropropyl, or similar halogenated alkyl group, preferred alkyl groups having from 1 to 6 carbons, especially methyl ethyl or propyl groups or phenyl groups. Preferably the silicon-bonded organic groups used in component (b) are alkyl groups, alternatively methyl, ethyl or propyl groups. Examples of the organosilicon compound having at least two, alternatively at least three Si-H groups per molecule (b) include but are not limited to: (a’) trimethylsiloxy-terminated methylhydrogenpolysiloxane, (b’) trimethylsiloxy-terminated polydimethylsiloxane-methylhydrogensiloxane, (c’) dimethylhydrogensiloxy-terminated dimethylsiloxane-methylhydrogensiloxane copolymers, (d’) dimethylsiloxane-methylhydrogensiloxane cyclic copolymers, (e’) copolymers and/or silicon resins consisting of (CH3)2HSiO1/2 units, (CH3)3SiO1/2 units and SiO4/2 units, (f’) copolymers and/or silicone resins consisting of (CH3)2HSiO1/2 units and SiO4/2 units, (g’) Methylhydrogensiloxane cyclic homopolymers having between 3 and 10 silicon atoms per molecule; alternatively, component (b), the cross-linker, may be a filler, e.g., silica treated with one of the above, and mixtures thereof. In one embodiment the Component (b) is selected from a methylhydrogenpolysiloxane capped at both molecular terminals with trimethylsiloxy groups; a copolymer of a methylhydrogensiloxane and a dimethylsiloxane capped at both molecular terminals with trimethylsiloxy groups; dimethylsiloxane capped at both molecular terminals with dimethylhydrogensiloxy groups; a copolymer of a methylhydrogensiloxane and a dimethylsiloxane capped at both molecular terminals with dimethylhydrogensiloxy groups. The cross-linker (b) is generally present in the hydrosilylation curable silicone rubber composition such that the molar ratio of the total number of the silicon-bonded hydrogen atoms in component (b) to the total number of alkenyl and/or alkynyl groups in component (a) is from 0.5 : 1.0 to 10.0 : 1.0. When this ratio is less than 0.5:1, a well-cured composition will not be obtained. When the ratio exceeds 10:1, there is a tendency for the hardness of the cured composition to increase when heated. Preferably component (b) is in an amount such that the molar ratio of silicon-bonded hydrogen atoms of component (b) to alkenyl/alkynyl groups, alternatively alkenyl groups of component (a) ranges from 0.7 : 1.0 to 5.0 : 1.0, alternatively from 0.9 : 1.0 to 2.5 : 1.0, and further alternatively from 0.9 : 1.0 to 2.0 : 1.0. The silicon-bonded hydrogen (Si-H) content of component (b) is determined using quantitative infra-red analysis in accordance with ASTM E168. In the present instance the silicon-bonded hydrogen to alkenyl (vinyl) and/or alkynyl ratio is important when relying on a hydrosilylation cure process. Generally, this is determined by calculating the total weight % of alkenyl groups in the composition, e.g., vinyl [V] and the total weight % of silicon bonded hydrogen [H] in the composition and given the molecular weight of hydrogen is 1 and of vinyl is 27 the molar ratio of silicon bonded hydrogen to vinyl is 27[H]/[V]. Typically, dependent on the number of unsaturated groups in component (a) as well as the number of Si-H groups in component (b), component (b) will be present in an amount of from 0.1 to 10 wt. % of the hydrosilylation curable silicone rubber composition, alternatively 0.1 to 7.5wt. % of the hydrosilylation curable silicone rubber composition, alternatively 0.5 to 7.5wt. %, further alternatively from 0.5% to 5 wt. % of the hydrosilylation curable silicone rubber composition. Component (c) Component (c) is a silica reinforcing filler which is optionally hydrophobically treated; The reinforcing fillers of component (c) may be exemplified by fumed silica and/or a precipitated silica and/or a colloidal silica. In one alternative, the fumed silica, precipitated silica and/or colloidal silica are provided in a finely divided form. Precipitated silica, fumed silica and/or colloidal silicas are particularly preferred because of their relatively high surface area, especially when provided in a finely divided form, which is typically at least 50 m²/g (BET method in accordance with ISO 9277: 2010). Fillers having surface areas of from 50 to 450 m²/g (BET method in accordance with ISO 9277: 2010), alternatively of from 50 to 300 m²/g (BET method in accordance with ISO 9277: 2010), are typically used. All these types of silica are commercially available. When silica reinforcing filler (c) is naturally hydrophilic (e.g., untreated silica fillers), it is typically treated with a treating agent to render it hydrophobic. These surface modified silica reinforcing fillers (c) do not clump and can be homogeneously incorporated into polydiorganosiloxane polymer (a), described below, as the surface treatment makes the fillers easily wetted by component (a). Typically, silica reinforcing filler (c) may be surface treated with any low molecular weight organosilicon compounds disclosed in the art applicable to prevent creping of liquid silicone rubber (LSR) compositions during processing. For example, organosilanes, polydiorganosiloxanes, or organosilazanes e.g., hexaalkyl disilazane, short chain siloxane diols to render the silica reinforcing filler (c) (s) hydrophobic and therefore easier to handle and obtain a homogeneous mixture with the other ingredients. Specific examples include, but are not restricted to, silanol terminated trifluoropropylmethylsiloxane, silanol terminated vinyl methyl (ViMe) siloxane, silanol terminated methyl phenyl (MePh) siloxane, liquid hydroxyldimethyl-terminated polydiorganosiloxane containing an average from 2 to 20 repeating units of diorganosiloxane in each molecule, hydroxyldimethyl terminated Phenylmethyl Siloxane, hexaorganodisiloxanes, such as hexamethyldisiloxane, divinyltetramethyldisiloxane; hexaorganodisilazanes, such as hexamethyldisilazane (HMDZ), divinyltetramethyldisilazane and tetramethyldi(trifluoropropyl)disilazane; hydroxyldimethyl terminated polydimethylmethylvinyl siloxane, octamethyl cyclotetrasiloxane, and silanes including but not limited to methyltrimethoxysilane, dimethyldimethoxysilane, vinyltrimethoxysilane, methyltriethoxysilane, vinyltriethoxysilane, chlorotrimethyl silane, dichlorodimethyl silane, trichloromethyl silane. In one embodiment, the treating agent may be selected from silanol terminated vinyl methyl (ViMe) siloxane, liquid hydroxyldimethyl-terminated polydiorganosiloxane containing an average from 2 to 20 repeating units of diorganosiloxane in each molecule, hexaorganodisiloxanes, such as hexamethyldisiloxane, divinyltetramethyldisiloxane; hexaorganodisilazanes, such as hexamethyldisilazane (HMDZ), divinyltetramethyldisilazane and; hydroxyldimethyl terminated polydimethylmethylvinyl siloxane, octamethyl cyclotetrasiloxane, and silanes including but not limited to methyltriethoxysilane, dimethyldiethoxysilane and/or vinyltriethoxysilane. A small amount of water can be added together with the silica treating agent(s) as processing aid. The surface treatment of untreated silica reinforcing filler (c) may be undertaken prior to introduction in the composition or in situ (i.e., in the presence of at least a portion of the other ingredients of the composition herein by blending these ingredients together at room temperature or above until the filler is completely treated. Typically, untreated silica reinforcing filler (c) is treated in situ with a treating agent in the presence of component (a) which results in the preparation of a silicone rubber base material which can subsequently be mixed with other ingredients. Silica reinforcing filler (c) is optionally present in an amount of up to 40 wt. % of the composition, alternatively from 1.0 to 40wt. % of the composition, alternatively of from 5.0 to 35wt. % of the composition, alternatively of from 10.0 to 35wt. % of the composition. Component (d) Component (d) of the composition is a hydrosilylation catalyst comprising or consisting of a platinum group metal or a compound thereof. These are usually selected from catalysts of the platinum group of metals (platinum, ruthenium, osmium, rhodium, iridium and palladium), or a compound of one or more of such metals. Alternatively, platinum and rhodium compounds are preferred due to the high activity level of these catalysts in hydrosilylation reactions, with platinum compounds most preferred. In a hydrosilylation (or addition) reaction a hydrosilylation catalyst such as component (d) herein catalyses the reaction between an unsaturated group, usually an alkenyl group e.g., vinyl with Si-H groups. The catalyst (d) can be a platinum group metal, a platinum group metal deposited on a carrier, such as activated carbon, metal oxides, such as aluminum oxide or silicon dioxide, silica gel or powdered charcoal, or a compound or complex of a platinum group metal. Preferably the platinum group metal is platinum. Examples of preferred hydrosilylation catalysts (d) are platinum based catalysts, for example, platinum black, platinum oxide (Adams catalyst), platinum on various solid supports, chloroplatinic acids, e.g., hexachloroplatinic acid (Pt oxidation state IV) (Speier catalyst), chloroplatinic acid in solutions of alcohols e.g., isooctanol or amyl alcohol (Lamoreaux catalyst), and complexes of chloroplatinic acid with ethylenically unsaturated compounds such as olefins and organosiloxanes containing ethylenically unsaturated silicon-bonded hydrocarbon groups, e.g., tetra-vinyl-tetramethylcyclotetrasiloxane- platinum complex (Ashby catalyst). Soluble platinum compounds that can be used include, for example, the platinum-olefin complexes of the formulae (PtCl2.(olefin)2 and H(PtCl3.olefin), preference being given in this context to the use of alkenes having 2 to 8 carbon atoms, such as ethylene, propylene, isomers of butene and of octene, or cycloalkanes having 5 to 7 carbon atoms, such as cyclopentene, cyclohexene, and cycloheptene. Other soluble platinum catalysts are, for the sake of example a platinum-cyclopropane complex of the formula (PtCl2C3H6)2, the reaction products of hexachloroplatinic acid with alcohols, ethers, and aldehydes or mixtures thereof, or the reaction product of hexachloroplatinic acid and/or its conversion products with vinyl-containing siloxanes such as methylvinylcyclotetrasiloxane in the presence of sodium bicarbonate in ethanolic solution –. Platinum catalysts with phosphorus and amine ligands can be used as well, e.g., (Ph3P)2PtCl2; and complexes of platinum with vinylsiloxanes, such as sym- divinyltetramethyldisiloxane. Hence, specific examples of suitable platinum-based catalysts include (i) complexes of chloroplatinic acid with organosiloxanes containing ethylenically unsaturated hydrocarbon groups are described in US 3,419,593; (ii) chloroplatinic acid, either in hexahydrate form or anhydrous form; (iii) a platinum-containing catalyst which is obtained by a method comprising reacting chloroplatinic acid with an aliphatically unsaturated organosilicon compound, such as divinyltetramethyldisiloxane; (iv) alkene-platinum-silyl complexes as described in US Pat. No.6,605,734 such as (COD)Pt(SiMeCl2)2 where “COD” is 1,5-cyclooctadiene; and/or (v) Karstedt's catalyst, a platinum divinyl tetramethyl disiloxane complex typically containing about 1 wt. % of platinum typically in a vinyl siloxane polymer with a viscosity of from about 200 to 750 mPa.s using the test methodology as described for component (a). Solvents such as toluene and the like organic solvents have been used historically as alternatives but the use of vinyl siloxane polymers by far the preferred choice. These are described in US3,715,334 and US3,814,730. In one preferred embodiment component (d) may be selected from co-ordination compounds of platinum. In one embodiment hexachloroplatinic acid and its conversion products with vinyl-containing siloxanes, Karstedt's catalysts and Speier catalysts are preferred. Component (d) is typically present in a quantity of platinum atom that provides from 0.1 to 500ppm (parts per million) with respect to the weight of the reactive ingredients, components (a) and (b). The catalyst may be added as a single species or as a mixture of two or more different species. Typically, dependent on the form/concentration in which the catalyst is provided the amount of catalyst present will be within the range of from 0.05–1.5 wt. % of the composition, alternatively from 0.05–1.0 wt. %, alternatively from 0.1–1.0 wt. %, alternatively 0.1 to 0.5 wt. %, of the composition, wherein the platinum catalyst is provided in a masterbatch of polymer such as (a) described above. Component (e) Component (e) of the hydrosilylation curable silicone rubber composition is a phthalocyanine compound or a metal derivative of such a compound, where the metal is copper, nickel, cobalt, iron, manganese, chromium, zinc, platinum, palladium or vanadium, for example the phthalocyanine compound may have the following structure: A metal phthalocyanine e.g., copper phthalocyanine is depicted below In one embodiment component (e) comprises or consists of copper phthalocyanine Any suitable form of copper phthalocyanine may be utilised e.g., the pigment 15:3 or 15:4 beta version of copper phthalocyanine , the 15.2 alpha form of copper phthalocyanine may also be used. The 15:1 alpha form of copper phthalocyanine is suitable when sufficiently stable. with the 15:3 or 15:4 beta version of copper phthalocyanine particularly preferred. Component (e) the phthalocyanine compound or a metal derivative of such a compound is present in an amount of from 0.02 wt. % to 2.5 wt. % of the composition, alternatively of from 0.1 wt. % to 2.5 wt. % of the composition, alternatively of from 0.2 wt. % to 2.0 wt. % of the composition.
AMENDED CLAIMS received by the International Bureau on 22 March 2024 (22.03.2024)

CLAIMS:

1) The UAV systems (Ref figure no: 1) can be as hexa copter, Octa copter, Quad copter,

VTOL, Fixed wing or any other type of unmanned aerial vehicle-UAV. a) The UAV comprises on board avionics Multi Axis/fixed gimble camera, thermal camera, IR visionary system, Onboard GPS system, megaphone speaker, mic, long range night vision torch light, multiple obstacle avoidance sensors and various aerial related sensors on its avionic board. b) In addition, the Day Light cameras (zoom/ adjustable/ fixed focal length), thermal cameras, IR Vision systems which helps for operational enhancement which works automatically or Remote monitored and controlled to identify victims, animals, specific objects, way path etc. c) The UAV having onboard battery backup which capable of quick swappable manner. On the other hand, ground battery conditioning station enables multiple battery charging with BMS units and enables battery cooling system (ventilation and/or cold conditioning system) with thermal and environmental protection casing. For multiple continuous drone operation with battery conditioning system in portable. d) The UAE can be made with modified frame structures and mounts which can made with materials like Carbon Fibre, Aluminium, Magnesium and other alloys. e) The remote control having the UAV control, a display, mini speaker, mic, Inbuilt battery with charger facilities and multiple channels of triggering switch. f) This UAV enables the emergency water landing facility with the help of floating buoyancy system fixed floater (ref sub dwg no:23) and or inflatable floaters (ref sub dwg no: 24). This floating buoyancy system can be mounted on the drones landing structure (Leg) and or to the Chassis frame as required as referred in figure no: 11. The buoyancy modules shall be automatic inflatable system and or fixed floater system. g) In here after rest of claims, the safety system to rescue the victims like Buoy, inflated floating units, Life Jacket, Inflatable Vests, Inflatable bag units, Inflatable boat and more will be referred as the Life safety system kit. Amendments of Claim 1: h) The additional LIDAR, RADAR, Multi and Hyper spectral cameras, Airborne Laser Scanning- ALS units and Electromagnetic sensor, Doppler Sensors unit can be mounted as singular or plurality in various axis in the same multi axis gimbal platform or in other places on the UAV as required for a precise operations for evaluating the distance, obstacles and identifying the specific targets in various methods of resulted data or sensor outputs by direct analysation or processed through Al from onboard processing units to the UAV to perform a safe flight and successful task for identification and rescue operations as referred in description for its operational performance. i) Various load Sensing devices like load sensor, weight sensors mounted on various parts on the UAV. This unit is connected to the onboard Avionics and processing unit to analyse and provide caution and restrictions to fly the UAV for operations. j) The UAVs data communication modules shall be Cellular networks (4G,5G,6G) and Special radio transceiving modules or can be through the satellite-based communication modules shall be used based on the operational requirements to the operations. k) The SoS alerting and signalling feature shall enable through the existing communication modules and also have separate communication modules such as WIFI, BLE, Long Ragne connectivity-LoRa and special RE Transceivers with modified capacity for auto tethering to provide the call for signals and Location coordinates to the user. Also providing the alerts like flash light, alarm sound and caution message to the nearby field after any accident or critical safe landing operation for the UAV. This system shall be separately powered by solar-powered systems and by onboard or secondary emergency batteries on its compartment to and integrated to the onboard avionics and processing unit to enable signalling and triggering the sos call from the UAV automatically to the nearby field and or to the users/operators. This system can also function as Flight Data Recorder (FDR) unit to the UAV for further investigation of the UAV.

2) The On-board Chip enables the operation through Al based Image Recognition, Object Tracking, Human and Animal Tracking with the help of the camera unit comprising a general camera or an IR or Thermal camera system. a) The drone receives the position of the victim and moves to the received position. The camera unit has a zoom-in and zoom-out function for shooting the state image of the victim while hovering in the air and clearly identifying the victims. b) The UAV controller and its onboard processing unit having a function of receiving a position information of the victim, the transceiver unit shall transmits the visual feed to the base monitor, and a controller controlling the state and operations. c) A drone including a feature that a virtual drop position is displayed on the photographed image and the position of the drone is finely adjusted by using a separate regulator to accurately position the dropping position of the Life safety system kit. d) This UAV onboard processing system enables the position tracking system for tracking the position of victim and other operation tasks and a drones, A display unit for displaying the image of the victim with the digital telescope in real time, a distance measuring unit for measuring the distance of the victim, a distance from the measured distance using the angle of the monitor and the height of the victim, A position tracking device including a control unit for calculating the position of uav and transceiver unit transmitting a path and altitude calculated by the drone, and an image/ visual feed receiving unit for receiving the visual image data taken through UAV then to the ground control and also to its onboard processing unit for further data process. e) Day light camera, Thermal imaging unit, IR Units shall enable for photographing the state of the victim in real time and a video transmitter for transmitting the data to the processing unit for enables the position tracking and manoeuvring to target point. f) Wherein the location tracking device comprises an adjustment function to adjust the UAV path and altitude based on an visual feed for enabling to analyse the condition of victim for accurate delivery of the Life safety system kits equipment.

3) As per the claim 1, Ref figure no: 2, 3. The Unmanned Aerial Vehicle (UAV) having the based lifesaving vests / buoy (lifesaving kits) dropping device. The UAV lifesaving kits dropping device comprises of a Life safety system kit which provides the connecting link from rescuer to victim. a) Wherein the connecting mechanism comprises the lifesaving kits which shall be fixed to the lower portion of the drone. The dropping mechanism is installed in the Life safety system kit fixing mechanism and comprises a steering motor, Connecting Rope Bundle Kit with rope release mechanism (ref sub dwg no: 17) and the control mechanism is installed on the lower portion of the UAV system. b) In the UAV based life buoy dropping device, the design of utilizing the baffles to block the life buoy is adopted, one or multiple life buoys can be accurately dropped multiple Life safety system kit for multiple times, and one unmanned aerial vehicle can rescue multiple targets during the operation. The core is to provide the interlinking mechanism between the victims and ground rescue team through a physical component (such as Ground connecting rope ref sub dwg no: 13, 15).

Amendments of Claim 3: c) The Guide unit shall be either a pully type, roller unit which is combined with the stopper unit mounted/attached with the connecting rope mechanism without any separate payload delivery release mechanism on UAV. While releasing the payload the guide unit will also release while dropping the payload.

4) From Ref figure no:5. The UAV shall provide the Life safety system kits connected with rope to the victim and another end of the ground connect kit to the rescuer nearby to safeguard the victim as quick operation. a) As per claim 4-a. the drone equipped with the connected rope bundle kit ref sub dwg no: 17, from which one end of the rope system is connected with safety belt jacket (ref sub dwg no: 15, 17). Then another end is connected with the rope bundle attached holder and the bundle rope system enables the inbuilt rope release mechanism as per figure no:5. b) UAV shall be operated by manual and/or by auto mode to identify the victims, then after the Drone reaches near to the victim who needs help and releases the rope which one end is connected the safety belt jacket (ref sub dwg no: 15 & 18) or lifesaving kits as referred in the claim no: 1-g. c) In ref to claim 4-b. after the release the Life safety system kits to victim the drone then releases the rope length also move towards the rescuer who is nearby then drone completely drops the bundle rope kit (ref sub dwg no: 17) to the rescuer. Then the rescuer shall tie the rope nearby point to hold victims or pulls back the victims to the safe location to rescue until the ground team reaches. d) In ref of figure no:6, The initial operation is referred from the claim no: 4c, Then after the releasing the Life safety system kits to victim. The UAV then release the length of rope towards its movement to between the mountain rocks, trees, ushes, other possible anchor holding node points and then it releases the complete rope bundle kit which another end connected with the collapsible grabbing hook type anchor system (ref sub dwg no: 19), From which the anchor hook holds the tightly, from this the victims can safely hold the life safety system kits and rope system to safeguard them until the ground or rescue team reaches. f. After the operation like claim no 4-d & e, The uav can be made to hover for visual live track the event or announcement on the air to the victim and to rescuer and/or the drone shall be taken to ground back as per the operational requirements.

5) From the figure no: 7, the rope bundle kit (ref sub dwg no: 17) attached to the UAV and both the end of the ropes is attached with the collapsible grabbing hook type anchor system (ref sub dwg no: 19). a) From Claim5, The UAV moves to the operational area through remotely operated and or by automatic method then the Drone releases the one end of the grabbing hook type Anchor kit (ref sub dwg no: 19) to between the mountain rocks, trees, bushes, other possible anchor holding node points and then it releases the rope length on its path to other area for making a rope line bridge from both end and then the Drone releases another end of the rope with the collapsible grabbing cook type anchor to between the mountain rocks, trees, Bushes, other possible anchor holding nodes after that the uav completely drops the rope bundle kit (ref sub dwg no: 17). b) From the claim 5-a & b, as ref figure no:7 the system thus makes a line of rope bridging between the two ends, where the victim or animal can able to hold the rope line bridge for the situations like flood or any mountain areas such as landslide and more to safeguard the victim until the rescue team reach to operation. Amendments of Claim 5:

C) As from ref figure no: 12, The Line thrower machine mounted on the UAV can used to throw collapsible grabbing hook type anchor system (ref sub dwg no: 19), line thrower if needed multiple line thrower machine can used to throw the grabbing hook type anchor system or other payload units. This unit shall be used for operations as per claim 3, 4, 5, 6, 7, 8, 9. d) as referred in claim 5c, the line thrower machine can be as air/gas-pressure thrower, electro-mechanical thrower and or chemical explosive-based thrower which shall be made by any metals or materials (eg. Metals, Alloys, Composite, Plastics, Woods etc). Also, this machine can be made as any type like gun model or other boxed model as the device mount can easily able to fix on the UAV along with the connecting rope bundle kit unit and payload. This unit can be triggered using electromechanical trigger unit inbuilt and connected to the UAV- Avionics and Onboard processing unit to the specific target or target trajectory based on the various sensor inputs (eg. GPS, Altitude Meter, Gyro and proxy meter, Avionic equipment’s etc.) and visionary units helps to aims target trajectory and trigger to throw the payload to the location either by Manual command and or by Al based Automatic triggering method for operations. Furthermore, this system can also perform to throw/deploy the other payload/plurality of payload such as Inflatable buoy/floating units and or other payload equipment’s without combining the connecting rope type system to the specific target at a certain altitude and distance.

6) As ref figure no: 8, The main “UAV- A” will have the regular operation kits as per the claim 1 ,2,3,4 on the other hand the supplementary “UAV-B” comprises the extension bundle kit (ref sub dwg no:20). a) As per the clime 6-a, standard system will help to extend the range of any operations as per the claim 1 ,2,3,4 after the specific task the drone releases the extender kit (ref sub dwg no:20) to link between the victim and the Drone operations independently for the further rescue operations as per the figure no :8, the ends of the rope can be notched or pined or pasted/fixed to connect the ends for the rescue operation. b) The ground connect rope kits rope material can be nylon, PVC, rubber blended type, other materials and the twist can be single or multiple twist rope can be made according to its operations. c) The power supply tethered wire can be attached to the connect rope ref sub dwg no: 17 by twisted in-betweens the rope or over attached or fixed etc.

7) As per ref figure no: 9, The multiple dropper kit with the universal Mount system comprises a processor / controller connected between the power supply and Drone area control board and the multiple payloads drop release like food packets, medicine kit, sanatory kit, other equipment’s etc. with the motor unit like stepper motor servo motor and or DC motor with its drive unit attached to the drone. a) When the Drone reaches to the specific task point can receive the triggering command either via remote control and or by automatic processed signal command, then it passes the release command to the processor by controller to activate the motors for payload release. b) The motor and the crossing control unit is having the power source mainly through onboard drone how are unit with BMS unit under by independent battery backup for the multiple release mechanism. These multiple drops can be controlled manually by same drone remote control or special control for the drop triggering unit. c) The processor by controller can activate we release of payload by individual or sequential order or by batch release more triggering the motor and drive unit according to the situation

8) The Ground connect system as referred in the ref sub dwg no: 12, Which the unit comprises Mechanical & Motorised winch, Connected rope kit (ref sub dwg no: 17), Omni directional rope release guide mechanism with stopper module. Which the ground connect system is made as weather proof, shockproof, portable, impact proof system. a) The ground system also comprises the power generator unit either gasoline, diesel or other oil-based units to power the drone and its modules in a tethered mode with power connection disengage module units. b) The ground system can be modified to have the power pack system of backup battery unit instead of oil-based power generating units referred in claim 8-a, To enables the power to UAV and its components in a tethered mode with power connection disengage system.

9) A power supply unit from ground connect system for supplying the necessary power to UAV through tethered mode as from power supply wires which fixed with connected rope kit unit to the module. a) A tension control unit for winding or unwinding a cable connecting the tethered drone and the ground station and a cable guide accommodating and controlling the cable and the connected rope kit ref sub dwg no: 13. b) The ground communication unit and the power supply unit are controlled to supply power to the tether drone through the cable, the tension control unit is controlled to adjust the length of the cable and the connected rope kit, and the cable guide is controlled to adjust the moving radius of the tether drone. c) The cable and the connected rope kit guide, A guide shaft shall be implemented as a multi-stage shaft to adjust the height of the cable and the connected rope kit guide, and a guide header rotatably connected to the guide shaft to control the cable so that the moving radius of the tethered drone is adjusted. d) Further comprising a roller for minimizing a friction force between the cable accommodated in the cable guide inside or outside, the guide shaft or the guide header, and a tension sensor for sensing the tension of the cable. The control unit, Controlling the tension control unit based on the current tension of the cable obtained from the tension sensor to adjust the tension of the cable. e) As ref of claim no: 8-a, The tethered power supply from the power generator unit in ground system ref sub dwg no: 12. The powering can be through either gasoline, diesel or other oil-based generation units to power the uav and its modules in a tethered mode with power connection disengage module and or the power pack system of backup battery unit instead of oil-based power generating units. f) Once the drone reached to the victim then it releases the payload connected to the rope connect system to the victims (Which rope and Tethered powering wire is attached/ blended throughout its rope range). During this release safety kit connect payload to victim’s operations as referred in ref figure no: 1,2,5,8,11. Then the power module in the drone connector disengages itself while triggering the payload operation manually or automatically from the drone and the ground station will automatically shut down the power supply to the wire rope.

10) As from ref figure no: 10, Then the UAV will fly near to the victim and drops the Motorised floating system like Motorised Buoy (ref sub dwg no:21) and Motorised Inflatable boat or bag (ref sub dwg no:22). *These systems can be used as singular or plurality to perform the operations as requires based on the special attachment and release mounts on the UAV as in claim 1.

Thus, it may help to rescue the victims from Ocean area, Dams, River, Water based areas and so on. In such a way the victim can catch the system and holds tightly, after that the rescuer or he ground team can able to operate the motorised floating system to take them back to the safe position additionally by viewing the visuals from drone and inbuild visual system in the motorised floating system to their remote controller display modules.

Description:
LIQUID SILICONE RUBBER COMPOSITION The present disclosure relates to hydrosilylation (addition) curable silicone rubber compositions, to silicone elastomeric materials with an improved high temperature (greater than or equal to (≥190 o C)) compression set in accordance with ISO 815-1 method A which are produced by curing said hydrosilylation (addition) curable silicone rubber compositions and to a method for preparing said silicone elastomeric materials. The present disclosure also extends to uses for such materials in or for the manufacture of silicone coatings for standard non-silicone insulators, as cable coatings e.g., for safety cables, in cable accessories such as electrical connectors, connector seals, terminations and wire seals, and for other electrical and electronic parts, particularly for the automotive industry and/or in or as hoses and gaskets for e.g., vehicle engines. Hydrosilylation curable silicone rubber compositions containing: (i) organopolysiloxane polymers having unsaturated (alkenyl and/or alkynyl) groups; (ii) compounds containing silicon-bonded hydrogen atoms; and (iii) a hydrosilylation catalyst are known in the art and are used to prepare silicone elastomeric materials with a broad spectrum of physical properties including electrical insulation, resistance and stability to heat, freeze resistance, abrasion resistance, fire retardancy, and long-term flexibility. This unique combination of properties renders elastomers made from liquid silicone rubber suitable for utilisation in a wide range of electrical and/or insulative applications, such as in or for electrical connectors, commonly used to create closed electrical circuits in automotive, residential, and infrastructural settings. For example, Silicone elastomers (both liquid silicone rubbers (LSRs) and high consistency rubbers (HCRs)) have been broadly utilized as seals in or for electrical connectors due to their excellent balance of mechanical properties, chemical and thermal stabilities and ease of processing. They may be used to mate rigid thermoplastic housing components forming a tight connection that provides both electrical and environmental isolation to connector junctions. These may be used in automotive vehicles which are becoming increasingly dependent on electrical and electronical systems for the full operation thereof, even more so since the introduction of electric and hybrid vehicles. Hence, electrical failures can lead to devices such as radio, light, ventilation etc. malfunctioning or breaking down. Many of the electrical connectors used for such devices rely on the aforementioned silicone rubber materials to prevent electrical failings and they need to be able to avoid failure in e.g., vehicles at increasing engine temperatures. Many of these applications require silicone elastomeric materials to have a low compression set in addition to their electrical insulation and/or heat stability etc applications. Compression set is a key property of silicone elastomeric materials utilized in any of the above applications. Compression set is a thermally induced fatigue behavior of a silicone elastomeric material which may be defined as the loss in ability of said silicone elastomeric material to recover to its original thickness after compression for specific period of time at a set (elevated) temperature. A compression set value may be measured, for example, following the industrial standard ISO 815-1:2019 methods A, B or C and is identified as a percentage, such that if there is complete recovery, i.e., if the thickness of a test specimen is identical before and after the application of a load, the compression set is 0%; if, in contrast, a 25% compression of a silicone elastomeric material applied during a test remains unchanged when the load is removed, the compression set is 100% because it has failed to return to its original shape at all. Without being tied to current theories, it is believed is believed that the root cause of the inability of a silicone-based elastomeric material to recover to its original thickness after compression over a specified period of time at a set (elevated) temperature is that hydrosilylation curable silicone compositions often, if not always, do not undergo complete cure during the standard curing process. This is thought to at least partially be because of incomplete hydrosilylation due to steric hindrance during interaction of vinyl containing silicone polymers, Si-H cross-linker(s) and hydrosilylation catalysts (most typically platinum based catalysts. Thus, when a hydrosilylation cured silicone elastomeric material is compressed at an elevated temperature, further cross-linking may occur within the body of the silicone elastomeric material specifically at previously unreacted Si-H positions. Additionally, inter-molecular bond formation can occur between polydimethylsiloxane (PDMS) chains, again particularly at previously unreacted Si-H excess positions (via hydrolysis, oxidative or thermally induced reaction pathways), and thermal, oxidative, and thermo-oxidative rearrangements may occur within or between individual PDMS chains of the silicone elastomeric material. The occurrence of one or more of the above will cause an increase in crosslink density within the silicone elastomeric material and consequently a more rigid structure which prevents the silicone elastomeric material to return to its original thickness after compression. Many silicone elastomeric materials have a substantial compression set e.g., of greater than 50% or even greater than 60% even after compression at temperatures of 125 o C and 150 o C for short periods of time e.g., 22 hours and can suffer from problems caused by a consequential change in shape and/or a significant increase in hardness during long-term service in high-temperature applications unless they undergo a post-cure heating process. “Post curing” is the most straightforward way to minimise compression set where hydrosilylation-cured silicone materials are subjected to a period of several hours e.g., four or more hours of post-cure heating at temperature of 150 o C or greater. However, post-curing is not usually commercially desired or indeed viable given increasing energy consumption and delays in manufacture time. Many applications described above typically desire silicone elastomeric materials having a compression set value which is as low a s possible e.g., no greater than 40%, across a wide spectrum of temperatures. In the United States electrical connector systems have to meet the requirements of the SAE International USCAR-2 “Performance Specification for Automotive Electrical Connector Systems” testing regime. Sealed connector assemblies are graded for their suitability for use over specified temperature ranges fulfilling a class of relevant automotive specifications for given temperature ranges. Currently there are five ranges identified as T1 – T5: T1 is for the temperature class -40° C to +85°C; T2 is for the temperature range -40° C to +100°C; T3 is for the temperature range -40° C to +125°C; T4 is for the temperature range -40° C to +150°C; and currently the highest grade is T5 for the -40° C to 175 °C. Current sealed connector assemblies are fulfilling the T3 temperature class. However, vehicle manufacturers are developing vehicles necessitating the need to withstand increased temperatures in vehicle engines and their surrounds due to, for example, better encapsulation, higher engine efficiency and turbocharger use etc. Hence, increasingly electrical connectors made from silicone rubber need to function at higher temperatures in order to meet T4 and T5 requirements. Given it is not desirable to be forced to post cure every elastomer after cure, a variety of additives have been proposed for the reduction of compression set without the need for post-cuing. In US5153244 compression set values of hydrosilylation cured silicone were substantially reduced by the introduction into said compositions of a phthalocyanine compound or a metal derivative of such a compound, where the metal was copper, nickel, cobalt or iron. US8080598B2 proposed a hydrosilylation cured silicone rubber having low compression set without post curing using a diacyl-hydrazide-based compound such as dodecanedioyl-di-(N′-salicyloyl)hydrazine, a synonym for which is 1-N',12-N'-bis(2-hydroxybenzoyl)dodecanedihydrazide, as well as several alternatives, in combination with a cure inhibitor selected from an acetylene-containing silane, a vinyl- containing low-molecular- weight organosiloxane compound, or an alcohol derivative having carbon- carbon triple bonds to reduce compression set. The introduction of US8080598B2 stated that “articles molded from an organopolysiloxane rubber composition curable by an addition reaction and compounded with a phthalocyanine compound have limited practical application because of coloration caused by the phthalocyanine”. Despite the teaching in US8080598B2, US9289963B2, US9598575B2 and US10000680B2 reverted back to the use of a phthalocyanine compound as a compression set additive. However, most of the previous compression set additives utilised, such as the above are suited for improving compression set after compression for at least 22 hours at up to the upper limit of T5 (+175 o C) and most current silicone elastomers made from LSRs mainly only fulfill Classes T3 (maximum 125°C) or T4 (maximum 150°C) requirements with compression set of less than or equal to (≤) 50% after compression over 1008h at the respective temperature. Hence, they are not able to act sufficiently well to reduce compression set for newer target performances with permanent test temperatures of 175°C (T5) which are increasingly being considered /proposed due to the ever- increasing demands of the automotive industry and others. There is provided herein a hydrosilylation curable silicone rubber composition, which comprises the following components: a) one or more polyorganosiloxanes containing at least two unsaturated groups, selected from alkenyl groups and alkynyl groups, per molecule and having a viscosity in a range of from 1000 mPa.s to 100,000 mPa.s at 25 o C; b) an organosilicon compound having at least two, alternatively at least three Si-H groups per molecule; c) a silica reinforcing filler which is optionally hydrophobically treated; d) a hydrosilylation catalyst comprising or consisting of a platinum group metal or a compound thereof; e) a phthalocyanine compound or a metal derivative of such a compound, where the metal is copper, nickel, cobalt, iron, manganese, chromium, zinc, platinum, palladium, and vanadium and which is present in an amount of from 0.02 wt. % to 2.5 wt. % of the composition; f) cyanuric acid, biuret or a mixture thereof in an amount of from 0.005 to 0.2 wt. % of the composition; and g) one or more of magnesium hydroxide, magnesium carbonate, magnesium hydroxy carbonate or manganese carbonate in an amount 0.25 to 2.0 wt. % of the composition; wherein the total wt. % of the composition is 100 wt. %. There is also provided a silicone elastomeric material which is the cured product of the above hydrosilylation curable silicone rubber composition, which silicone elastomeric material has a compression set of no more than 15%, preferably no more than 10% when measured in accordance with industrial standard norm ISO 815-1 method A after compression at 175 o C for 22 hours and a compression set of no more than 20%, preferably no more than 15% when measured in accordance with industrial standard norm ISO 815-1 method A after compression at 200 o C for 22 hours; alternatively having a compression set of 30 % or less, preferably 25 % or less, when measured in accordance with industrial standard norm ISO 815-1 method A after compression at 175 o C for 168 hours and a compression set of 40 % or less, preferably 35 % or less, when measured in accordance with industrial standard norm ISO 815-1 method A after compression at 200 o C for 168 hours (one week). There is also provided a process for making a silicone elastomeric material comprising the steps of mixing: a) one or more polyorganosiloxanes containing at least two unsaturated groups, selected from alkenyl groups and alkynyl groups, per molecule and having a viscosity in a range of from 1000 mPa.s to 100,000 mPa.s at 25 o C; b) an organosilicon compound having at least two, alternatively at least three Si-H groups per molecule; c) a silica reinforcing filler which is optionally hydrophobically treated; d) a hydrosilylation catalyst comprising or consisting of a platinum group metal or a compound thereof; e) a phthalocyanine compound or a metal derivative of such a compound, where the metal is copper, nickel, cobalt, iron, manganese, chromium, zinc, platinum, palladium, and vanadium and which is present in an amount of from 0.02 wt. % to 2.5 wt. % of the composition; f) cyanuric acid, biuret or a mixture thereof in an amount of from 0.005 to 0.2 wt. % of the composition; and g) one or more of magnesium hydroxide, magnesium carbonate, magnesium hydroxy carbonate or manganese carbonate in an amount 0.25 to 2.0 wt. % of the composition; and curing the composition at a temperature of from 80 o C to 200 o C. There is also provided a silicone elastomeric material obtained or obtainable from a process comprising the steps of mixing a: a) one or more polyorganosiloxanes containing at least two unsaturated groups, selected from alkenyl groups and alkynyl groups, per molecule and having a viscosity in a range of from 1000 mPa.s to 100,000 mPa.s at 25 o C; b) an organosilicon compound having at least two, alternatively at least three Si-H groups per molecule; c) a silica reinforcing filler which is optionally hydrophobically treated; d) a hydrosilylation catalyst comprising or consisting of a platinum group metal or a compound thereof; e) a phthalocyanine compound or a metal derivative of such a compound, where the metal is copper, nickel, cobalt, iron, manganese, chromium, zinc, platinum, palladium, and vanadium and which is present in an amount of from 0.02 wt. % to 2.5 wt. % of the composition; f) cyanuric acid, biuret or a mixture thereof in an amount of from 0.005 to 0.2 wt. % of the composition; and g) one or more of magnesium hydroxide, magnesium carbonate, magnesium hydroxy carbonate or manganese carbonate in an amount 0.25 to 2.0 wt. % of the composition; wherein the total wt. % of the composition is 100 wt. %; and curing the composition at a temperature of from 80 o C to 200 o C; which silicone elastomeric material has a compression set of no more than 20% after 22 hours compression at temperatures up to 190 o C, alternatively up to 200 o C, when measured in accordance with industrial standard norm ISO 815-1:2019 method A. There is also provided the use of a combination of components (e) (f) and (g) wherein e) is a phthalocyanine compound or a metal derivative of such a compound, where the metal is copper, nickel, cobalt, iron, manganese, chromium, zinc, platinum, palladium, and vanadium; f) is cyanuric acid, biuret or a mixture thereof in an amount of from 0.005 to 0.2 wt. % of the composition; and g) is one or more of magnesium hydroxide, magnesium carbonate, magnesium hydroxy carbonate or nd a groups. Alternatively, component (a) has at least three unsaturated groups per molecule. The unsaturated groups of component (a) may be terminal, pendent, or in both locations.